有机长持续发光的最新进展:设计策略和内部机制

Jie Yang, Zhijian Chen, Manman Fang, Zhen Li
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摘要

有机余辉材料因其在实际应用中的巨大潜力而日益受到关注。迄今为止,大多数有机余辉材料的寿命仅为毫秒或几秒,而要实现持续数分钟甚至数小时的长持续发光(LPL)却十分困难。2017 年,Adachi 和 Kabe 成功在纯有机体系中实现了持续时间超过 1 小时的 LPL,甚至可以与一些优秀的无机材料相媲美。然而,部分由于结构-性能关系不明确,有机 LPL 材料仍然相当匮乏,尤其是在空气或水溶液中稳定的有机 LPL 材料。在这篇综述中,我们介绍了有机 LPL 的最新进展,主要集中在材料设计策略和内部机理方面。希望对这些问题的深入理解有助于进一步开发在空气甚至水相中具有良好稳定性的有机 LPL 材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Recent advances of organic long persistent luminescence: Design strategy and internal mechanism
Organic afterglow materials have drawn increasing attention for their great potential in practical applications. Until now, most of them just show the lifetimes in milliseconds or seconds, while the realization of long persistent luminescence (LPL) lasting for minutes or even hours is difficult. In 2017, Adachi and Kabe successfully realize the LPL with a duration longer than 1 hour in a purely organic system, which can be even comparable to some excellent inorganic materials. However, partially for the unclear structure-property relationship, organic LPL materials are still rather scarce, especially for the stable ones in air or aqueous solution. In this review, we present the recent progress in organic LPL, mainly focusing on the material design strategy and internal mechanism. It is anticipated that the deep understanding can be beneficial for the further development of organic LPL materials with good stability in air and even aqueous phase.
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