作为光激发发光剂量计的金属有机框架

IF 1.5 3区 化学 Q3 CHEMISTRY, ANALYTICAL Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2024-09-16 DOI:10.1007/s10967-024-09761-7
Shailesh Joshi, Madhusmita Panda, O. Annalakshmi, C. Venkata Srinivas, B. Venkatraman
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摘要

近几十年来,金属有机框架(MOF)作为杂化材料受到了广泛的研究,因为它们具有特殊的结构多样性,并可应用于多个领域。开发用于辐射检测和基于发光的剂量测定的新型 MOF 是最新的研究课题。在本文中,我们合成并表征了一种铀MOF,它在电离辐射的诱导下显示出光激发发光(OSL)现象。我们对铀基 MOF 进行了剂量测定研究,结果表明 MOF 具有高达 100 Gy 的线性剂量响应,最小检测剂量为 1.1 Gy。它还显示出良好的重复使用性,一天内衰减约 30%,一天后至 30 天内衰减极低,辐射稳定性良好(稳定达 10 kGy)。初步剂量测定结果很有希望,表明铀 MOF 未来可用于低剂量辐射处理应用领域。
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Metal–organic frameworks as optically stimulated luminescence dosimeter

Metal–organic frameworks (MOF) have been vigorously investigated as hybrid materials in recent decades due to their exceptional structural versatility and applications in diverse fields. The development of novel MOFs for radiation detection and luminescence-based dosimetry is the latest topic of interest. In this contribution, we have synthesized and characterized a Uranyl MOF, which shows an optically stimulated luminescence (OSL) phenomenon induced by ionizing radiation. OSL dosimetric studies were carried out on Uranyl MOF, which revealed that MOF has a linear dose–response up to 100 Gy with a 1.1 Gy minimum detection dose. It also shows good reusability, around 30% fading in one day, very low fading beyond one day to 30 days, and decent radiation stability (stable up to 10 kGy). Preliminary dosimetry results are promising and show that Uranyl MOF can be utilized in the field of low-dose radiation processing applications in the future.

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来源期刊
CiteScore
2.80
自引率
18.80%
发文量
504
审稿时长
2.2 months
期刊介绍: An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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