通过碘离子在网络中的插层将珊瑚礁状的 AgI/ 聚吡咯纳米复合材料应用于光电领域

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-09-14 DOI:10.1002/ep.14475
Mohamed Rabia, Asmaa M. Elsayed, Eman Aldosari, Ahmed Adel A. Abdelazeez
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引用次数: 0

摘要

我们制造出了一种用于紫外线和可见光区域光感应的前景广阔的光电设备。该器件由一种类似珊瑚礁的纳米复合材料组成,称为 AgI/聚吡咯-碘化物(AgI/Ppy-I)。由此产生的纳米复合材料呈现出一种分层结构,其中较大的颗粒由约 45 nm 的较小颗粒组成,光带隙为 2.4 eV,形成类似珊瑚礁的形态。对这种构建的光电器件的灵敏度估计依赖于对电流密度(Jph)值的评估。在光照条件下,电流密度(Jph = 0.46 mA cm-2)明显增加,与黑暗条件下的 0.12 mA cm-2 相比,其值很有希望。这种纳米复合材料的光学特性非常有利于实现高效的紫外可见光传感。在紫外区和可见光区,反映器件灵敏度的 D 值(检测率)分别高达 4 × 108 琼斯和 3.82 × 108 琼斯。计算得出的 R 值(表示器件的响应度)进一步证实了这种光电探测器的潜力。这两个光学区域的响应值分别为 1.8 mA W-1 和 1.72 mA W-1,这表明纳米复合材料能有效地将入射光转化为电流。此外,这种光电探测器的吸引力还不止于其性能特点。它具有成本效益、环保、制备方法简单、可大规模生产以及高稳定性等特点。这种材料的多功能性加上其优势特性,为其广泛应用开辟了道路,满足了各行各业的不同需求,并有助于为更多人提供高效的光电设备。
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Coral reefs‐like shape AgI/polypyrrole nanocomposite through the intercalation of iodide ions in the network for optoelectronic applications
A promising optoelectronic device for light sensing in both the UV and Vis regions is fabricated. This device consists of a nanocomposite resembling coral reefs, termed AgI/polypyrrole‐iodide (AgI/Ppy‐I). The resulting nanocomposite exhibits a hierarchical structure wherein larger particles, comprising smaller particles ~45 nm and an optical bandgap measuring 2.4 eV, form a coral reef‐like morphology. The sensitivity estimation of this constructed optoelectronic device relies on evaluating the current density (Jph) values. Under illumination, a remarkable augmentation in current density (Jph = 0.46 mA cm−2) with a promising value compared to the dark condition's 0.12 mA cm−2. The optical characteristics of this nanocomposite make it highly conducive to efficient UV–Vis light sensing. The values of D (detectivity), reflecting the device's sensitivity, are notably high at 4 × 108 and 3.82 × 108 Jones in the UV and Vis regions, correspondingly. The potential of this photodetector is reinforced by the computed R‐values, which denote the device's responsivity. With values of 1.8 and 1.72 mA W−1 across these two optical regions, correspondingly, it showcases the nanocomposite's effectiveness in transforming incident light into electrical current. Moreover, the appeal of this photodetector extends beyond its performance characteristics. Its cost‐effectiveness, eco‐friendliness, straightforward preparation methodology, scalability for mass production, and high stability collectively. The versatility of this material, coupled with its advantageous attributes, opens avenues for its widespread application, catering to the diverse needs of industries and contributing to the accessibility of efficient optoelectronic devices for a broader audience.
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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