用于环境和水应用的 3D 打印技术

Sheng Guo, Yifu Ding, Kun Zhou
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In response to this trend, we are honored to publish this new special issue entitled “3D Printing Technologies for Environmental and Water Applications” in <i>ACS ES&amp;T Water</i> showcasing the latest reviews, advancements, and challenges encountered in applying 3D-printing technologies to address environmental and water-related issues. This special issue includes two review papers, eight research articles, and a viewpoint article covering a wide spectrum of environmental and water-related topics: (1) water treatment via adsorption, photocatalysis, and advanced oxidation processes, (2) environmental detection, (3) design of environmental devices, and (4) membrane separation. Majooni et al. (1) presented a comprehensive overview of 3D-printed nanomaterials utilized in water treatment and highlighted the critical role of nanoenabled 3D-printed structures in improving conventional water treatment strategies. Meanwhile, Ibrahim and Hilal (2) summarized the positive aspects of surface patterning of membranes on their performances, indicating that upon overcoming the challenges of material compatibility, reproducibility, and limited resolution, 3D-printing technologies will hold great potential to enhance membrane performances in the domain of water treatment. In the work of Fung et al., (3) the microstreaming behaviors of air bubbles trapped in 3D-printed Helmholtz structures were explored, revealing that acoustically induced fluidic streaming can potentially be employed to mitigate membrane fouling, which constitutes the most significant problem in membrane processes. In their article, Wang et al. (4) emphasized that further research should prioritize advancements in 3D-printing software, innovation in the design of printable structures, the expansion of 3D-printable material options, and optimizing the efficiency of 3D printers. These endeavors are essential for facilitating the widespread application of 3D-printing technologies and accelerating their development in membrane-related research fields. Peroxymonosulfate (PMS)- and sulfite [S(IV)]-based advanced oxidation processes (AOPs) are effective strategies for addressing the issue of water pollution. Inspired by these approaches, Guo et al. (5) and Yang et al. (6) developed novel 3D hierarchical porous copper (3D-Cu) catalysts for degrading antibiotics through PMS and S(IV) activation, respectively. Notably, both catalysts can maintain high performance with respect to tetracycline hydrochloride (TC) even after 40 successive cycles. Meanwhile, titanium dioxide (TiO<sub>2</sub>), commonly acknowledged as the most promising photocatalyst for wastewater treatment due to its wide availability, high chemical stability, and corrosion resistance, was selected as the basis of the works of Wei et al. (7) and Chen et al., (8) who utilized 3D printing to construct nanoporous-TiO<sub>2</sub>-encapsulating microporous-double-gyroid-structure photocatalysts and diamond-structured TiO<sub>2</sub> reactors to degrade antibiotics and organic synthetic dyes, respectively. Both of the as-printed catalysts demonstrated remarkable durability and reusability, which can be attributed to their stable 3D structures. Beyond water treatment, 3D-printing technologies have also been implemented in contamination detection in aquatic environments. For example, Paré et al. (9) applied the direct ink writing (DIW) method to introduce single-walled carbon nanotube (SWCNT)/polylactic acid ink to graphite electrodes, resulting in their increased sensitivity and resistance to sulfur poisoning. Similarly, Liu et al. (10) designed a 3D-printed, smartphone-assisted acute toxicity detector capable of rapidly assessing the inhibition rate of luminescent bacteria, which offers an efficient and cost-effective approach for immediate acute toxicity evaluation. In addition, Monaghan (11) developed low-cost automatic sampler and data processing software using a 3D printer and the software Matlab. This system enables the automated and high-throughput analysis of tire-derived <i>p</i>-phenylenediamine quinones (PPDQs) in water through the implementation of online membrane sampling coupled with mass spectrometry technology. In summary, this special issue highlights the diverse applications of 3D-printing technologies in tackling environmental challenges, primarily within the expansive realm of water-related topics. As guest editors of this special issue, we extend our deep appreciation to Dr. Shane Snyder, Editor-in-Chief of <i>ACS ES&amp;T Water</i>, and Dr. Ching-Hua Huang, Associate Editor of <i>ACS ES&amp;T Water</i>, for their invaluable editorial support. We are also grateful to Dr. Margaret Mills, Managing Editor of <i>ACS ES&amp;T Water</i>, for her meticulous handling of this special issue as well as all of the authors and reviewers for their sincere and significant contributions. We hope that this special issue will inspire a broader spectrum of researchers to embrace and integrate innovative 3D-printing technologies into water-related environmental fields and offer scientifically robust and technologically advanced solutions for the protection and/or detection of contaminants in aquatic environments, as well as the efficient utilization of water resources. <b>Dr. Sheng Guo</b> is a Professor of Environmental Engineering in the State Key Laboratory of New Textile Materials &amp; Advanced Processing Technologies at Wuhan Textile University. He received his Ph.D. from Wuhan University of Technology in 2015 and served as a postdoctoral researcher at Nanyang Technological University from 2018 to 2020. His research focuses on the synthesis, characterization, and applications of fibers, metallic oxides, and 3D-printed materials. <b>Dr. Yifu Ding</b> is a professor in the Paul M. Rady Department of Mechanical Engineering at the University of Colorado Boulder. He received his B.S. degree in polymer science and engineering from Fudan University, followed by a Ph.D. from the University of Akron, with an emphasis on spectroscopic studies of polymer dynamics. After three years of postdoctoral research at the National Institute of Standards and Technology (NIST), Dr. Ding joined the University of Colorado Boulder in 2008. His research interests include surface and interfacial properties of polymers with applications in membrane technologies. Dr. Ding currently serves as the director for the University of Colorado Boulder site of the Membrane Application Science and Technology (MAST) center, a National Science Foundation Industry University Collaborative Research Center (IUCRC). <b>Dr. Kun Zhou</b> is a Professor of Mechanical Engineering in the School of Mechanical and Aerospace Engineering at Nanyang Technological University, Singapore. He currently serves as Programme Director (Marine &amp; Offshore) of the Singapore Centre for 3D Printing. He received his B.Eng. and M.Eng. degrees from Tsinghua University, China, and his Ph.D. from Nanyang Technological University. He has been conducting multidisciplinary research at the crossroads of mechanics, additive manufacturing, materials science, and molecular physics. He is a Fellow of the European Academy of Sciences. This article references 11 other publications. 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Due to their cost-effectiveness, rapid production, and precise control over target structures, 3D-printing technologies have gained widespread attention and have been extensively applied in various environmental and water-related applications, such as environmental detection, wastewater treatment, water splitting, oil–water separation, and desalination. In response to this trend, we are honored to publish this new special issue entitled “3D Printing Technologies for Environmental and Water Applications” in <i>ACS ES&amp;T Water</i> showcasing the latest reviews, advancements, and challenges encountered in applying 3D-printing technologies to address environmental and water-related issues. This special issue includes two review papers, eight research articles, and a viewpoint article covering a wide spectrum of environmental and water-related topics: (1) water treatment via adsorption, photocatalysis, and advanced oxidation processes, (2) environmental detection, (3) design of environmental devices, and (4) membrane separation. Majooni et al. (1) presented a comprehensive overview of 3D-printed nanomaterials utilized in water treatment and highlighted the critical role of nanoenabled 3D-printed structures in improving conventional water treatment strategies. Meanwhile, Ibrahim and Hilal (2) summarized the positive aspects of surface patterning of membranes on their performances, indicating that upon overcoming the challenges of material compatibility, reproducibility, and limited resolution, 3D-printing technologies will hold great potential to enhance membrane performances in the domain of water treatment. In the work of Fung et al., (3) the microstreaming behaviors of air bubbles trapped in 3D-printed Helmholtz structures were explored, revealing that acoustically induced fluidic streaming can potentially be employed to mitigate membrane fouling, which constitutes the most significant problem in membrane processes. In their article, Wang et al. (4) emphasized that further research should prioritize advancements in 3D-printing software, innovation in the design of printable structures, the expansion of 3D-printable material options, and optimizing the efficiency of 3D printers. These endeavors are essential for facilitating the widespread application of 3D-printing technologies and accelerating their development in membrane-related research fields. Peroxymonosulfate (PMS)- and sulfite [S(IV)]-based advanced oxidation processes (AOPs) are effective strategies for addressing the issue of water pollution. Inspired by these approaches, Guo et al. (5) and Yang et al. (6) developed novel 3D hierarchical porous copper (3D-Cu) catalysts for degrading antibiotics through PMS and S(IV) activation, respectively. Notably, both catalysts can maintain high performance with respect to tetracycline hydrochloride (TC) even after 40 successive cycles. Meanwhile, titanium dioxide (TiO<sub>2</sub>), commonly acknowledged as the most promising photocatalyst for wastewater treatment due to its wide availability, high chemical stability, and corrosion resistance, was selected as the basis of the works of Wei et al. (7) and Chen et al., (8) who utilized 3D printing to construct nanoporous-TiO<sub>2</sub>-encapsulating microporous-double-gyroid-structure photocatalysts and diamond-structured TiO<sub>2</sub> reactors to degrade antibiotics and organic synthetic dyes, respectively. Both of the as-printed catalysts demonstrated remarkable durability and reusability, which can be attributed to their stable 3D structures. Beyond water treatment, 3D-printing technologies have also been implemented in contamination detection in aquatic environments. For example, Paré et al. (9) applied the direct ink writing (DIW) method to introduce single-walled carbon nanotube (SWCNT)/polylactic acid ink to graphite electrodes, resulting in their increased sensitivity and resistance to sulfur poisoning. Similarly, Liu et al. (10) designed a 3D-printed, smartphone-assisted acute toxicity detector capable of rapidly assessing the inhibition rate of luminescent bacteria, which offers an efficient and cost-effective approach for immediate acute toxicity evaluation. In addition, Monaghan (11) developed low-cost automatic sampler and data processing software using a 3D printer and the software Matlab. 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引用次数: 0

摘要

三维(3D)打印,又称增材制造,是一种多功能制造技术,几乎可以制造任何几何形状复杂的物体。由于其成本效益高、生产速度快、目标结构控制精确,三维打印技术受到广泛关注,并被广泛应用于各种环境和水相关领域,如环境检测、废水处理、水分离、油水分离和海水淡化等。针对这一趋势,我们很荣幸地在 ACS ES&amp;T Water 上出版这本题为 "3D 打印技术在环境和水领域的应用 "的新特刊,展示在应用 3D 打印技术解决环境和水相关问题方面的最新评论、进展和遇到的挑战。本特刊包括两篇综述论文、八篇研究文章和一篇观点文章,涵盖了环境和水相关的广泛主题:(1) 通过吸附、光催化和高级氧化过程进行水处理,(2) 环境检测,(3) 环境设备设计,以及 (4) 膜分离。Majooni 等人(1)全面概述了水处理中使用的三维打印纳米材料,并强调了纳米三维打印结构在改进传统水处理策略中的关键作用。同时,Ibrahim 和 Hilal(2)总结了膜表面图案化对其性能的积极影响,指出在克服材料兼容性、可重复性和有限分辨率等挑战后,三维打印技术将在提高水处理领域的膜性能方面拥有巨大潜力。Fung 等人的研究(3)探讨了被困在三维打印赫尔姆霍兹结构中的气泡的微流行为,揭示了声学诱导的流体流可能被用来减轻膜污垢,而膜污垢是膜过程中最重要的问题。Wang 等人(4)在他们的文章中强调,进一步的研究应优先考虑三维打印软件的进步、可打印结构设计的创新、三维打印材料选择的扩展以及三维打印机效率的优化。这些努力对于促进 3D 打印技术的广泛应用和加快其在膜相关研究领域的发展至关重要。基于过一硫酸盐(PMS)和亚硫酸盐[S(IV)]的高级氧化过程(AOPs)是解决水污染问题的有效策略。受这些方法的启发,Guo 等人(5)和 Yang 等人(6)分别开发了新型三维分层多孔铜(3D-Cu)催化剂,通过 PMS 和 S(IV)活化降解抗生素。值得注意的是,这两种催化剂对盐酸四环素(TC)都能保持较高的性能,即使在连续循环 40 次之后也是如此。同时,二氧化钛(TiO2)因其广泛的可用性、高度的化学稳定性和耐腐蚀性,被公认为最有前途的废水处理光催化剂,Wei 等人(7)和 Chen 等人(8)分别利用 3D 打印技术构建了纳米多孔-TiO2-封装微孔-双甲状腺结构光催化剂和金刚石结构 TiO2 反应器,用于降解抗生素和有机合成染料。这两种按原样打印的催化剂都表现出卓越的耐久性和可重复使用性,这归功于它们稳定的三维结构。除了水处理,三维打印技术还被应用于水生环境的污染检测。例如,Paré 等人(9)应用直接墨水书写(DIW)方法将单壁碳纳米管(SWCNT)/聚乳酸墨水引入石墨电极,从而提高了石墨电极的灵敏度和抗硫中毒能力。同样,Liu 等人(10)设计了一种三维打印的智能手机辅助急性毒性检测器,能够快速评估发光细菌的抑制率,为即时急性毒性评估提供了一种高效、经济的方法。此外,Monaghan(11)利用三维打印机和 Matlab 软件开发了低成本自动采样器和数据处理软件。该系统通过实施在线膜采样和质谱技术,实现了对水中轮胎衍生对苯二胺醌(PPDQs)的自动化和高通量分析。总之,本特刊重点介绍了三维打印技术在应对环境挑战方面的各种应用,主要是在与水有关的广泛领域。作为本特刊的特邀编辑,我们向裴斯泰洛齐博士表示深深的谢意。
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3D-Printing Technologies for Environmental and Water Applications
Three-dimensional (3D) printing, also termed additive manufacturing, is a versatile fabrication technique capable of constructing virtually any geometrically complex object. Due to their cost-effectiveness, rapid production, and precise control over target structures, 3D-printing technologies have gained widespread attention and have been extensively applied in various environmental and water-related applications, such as environmental detection, wastewater treatment, water splitting, oil–water separation, and desalination. In response to this trend, we are honored to publish this new special issue entitled “3D Printing Technologies for Environmental and Water Applications” in ACS ES&T Water showcasing the latest reviews, advancements, and challenges encountered in applying 3D-printing technologies to address environmental and water-related issues. This special issue includes two review papers, eight research articles, and a viewpoint article covering a wide spectrum of environmental and water-related topics: (1) water treatment via adsorption, photocatalysis, and advanced oxidation processes, (2) environmental detection, (3) design of environmental devices, and (4) membrane separation. Majooni et al. (1) presented a comprehensive overview of 3D-printed nanomaterials utilized in water treatment and highlighted the critical role of nanoenabled 3D-printed structures in improving conventional water treatment strategies. Meanwhile, Ibrahim and Hilal (2) summarized the positive aspects of surface patterning of membranes on their performances, indicating that upon overcoming the challenges of material compatibility, reproducibility, and limited resolution, 3D-printing technologies will hold great potential to enhance membrane performances in the domain of water treatment. In the work of Fung et al., (3) the microstreaming behaviors of air bubbles trapped in 3D-printed Helmholtz structures were explored, revealing that acoustically induced fluidic streaming can potentially be employed to mitigate membrane fouling, which constitutes the most significant problem in membrane processes. In their article, Wang et al. (4) emphasized that further research should prioritize advancements in 3D-printing software, innovation in the design of printable structures, the expansion of 3D-printable material options, and optimizing the efficiency of 3D printers. These endeavors are essential for facilitating the widespread application of 3D-printing technologies and accelerating their development in membrane-related research fields. Peroxymonosulfate (PMS)- and sulfite [S(IV)]-based advanced oxidation processes (AOPs) are effective strategies for addressing the issue of water pollution. Inspired by these approaches, Guo et al. (5) and Yang et al. (6) developed novel 3D hierarchical porous copper (3D-Cu) catalysts for degrading antibiotics through PMS and S(IV) activation, respectively. Notably, both catalysts can maintain high performance with respect to tetracycline hydrochloride (TC) even after 40 successive cycles. Meanwhile, titanium dioxide (TiO2), commonly acknowledged as the most promising photocatalyst for wastewater treatment due to its wide availability, high chemical stability, and corrosion resistance, was selected as the basis of the works of Wei et al. (7) and Chen et al., (8) who utilized 3D printing to construct nanoporous-TiO2-encapsulating microporous-double-gyroid-structure photocatalysts and diamond-structured TiO2 reactors to degrade antibiotics and organic synthetic dyes, respectively. Both of the as-printed catalysts demonstrated remarkable durability and reusability, which can be attributed to their stable 3D structures. Beyond water treatment, 3D-printing technologies have also been implemented in contamination detection in aquatic environments. For example, Paré et al. (9) applied the direct ink writing (DIW) method to introduce single-walled carbon nanotube (SWCNT)/polylactic acid ink to graphite electrodes, resulting in their increased sensitivity and resistance to sulfur poisoning. Similarly, Liu et al. (10) designed a 3D-printed, smartphone-assisted acute toxicity detector capable of rapidly assessing the inhibition rate of luminescent bacteria, which offers an efficient and cost-effective approach for immediate acute toxicity evaluation. In addition, Monaghan (11) developed low-cost automatic sampler and data processing software using a 3D printer and the software Matlab. This system enables the automated and high-throughput analysis of tire-derived p-phenylenediamine quinones (PPDQs) in water through the implementation of online membrane sampling coupled with mass spectrometry technology. In summary, this special issue highlights the diverse applications of 3D-printing technologies in tackling environmental challenges, primarily within the expansive realm of water-related topics. As guest editors of this special issue, we extend our deep appreciation to Dr. Shane Snyder, Editor-in-Chief of ACS ES&T Water, and Dr. Ching-Hua Huang, Associate Editor of ACS ES&T Water, for their invaluable editorial support. We are also grateful to Dr. Margaret Mills, Managing Editor of ACS ES&T Water, for her meticulous handling of this special issue as well as all of the authors and reviewers for their sincere and significant contributions. We hope that this special issue will inspire a broader spectrum of researchers to embrace and integrate innovative 3D-printing technologies into water-related environmental fields and offer scientifically robust and technologically advanced solutions for the protection and/or detection of contaminants in aquatic environments, as well as the efficient utilization of water resources. Dr. Sheng Guo is a Professor of Environmental Engineering in the State Key Laboratory of New Textile Materials & Advanced Processing Technologies at Wuhan Textile University. He received his Ph.D. from Wuhan University of Technology in 2015 and served as a postdoctoral researcher at Nanyang Technological University from 2018 to 2020. His research focuses on the synthesis, characterization, and applications of fibers, metallic oxides, and 3D-printed materials. Dr. Yifu Ding is a professor in the Paul M. Rady Department of Mechanical Engineering at the University of Colorado Boulder. He received his B.S. degree in polymer science and engineering from Fudan University, followed by a Ph.D. from the University of Akron, with an emphasis on spectroscopic studies of polymer dynamics. After three years of postdoctoral research at the National Institute of Standards and Technology (NIST), Dr. Ding joined the University of Colorado Boulder in 2008. His research interests include surface and interfacial properties of polymers with applications in membrane technologies. Dr. Ding currently serves as the director for the University of Colorado Boulder site of the Membrane Application Science and Technology (MAST) center, a National Science Foundation Industry University Collaborative Research Center (IUCRC). Dr. Kun Zhou is a Professor of Mechanical Engineering in the School of Mechanical and Aerospace Engineering at Nanyang Technological University, Singapore. He currently serves as Programme Director (Marine & Offshore) of the Singapore Centre for 3D Printing. He received his B.Eng. and M.Eng. degrees from Tsinghua University, China, and his Ph.D. from Nanyang Technological University. He has been conducting multidisciplinary research at the crossroads of mechanics, additive manufacturing, materials science, and molecular physics. He is a Fellow of the European Academy of Sciences. This article references 11 other publications. This article has not yet been cited by other publications.
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