硼金属氧化物水平二维燃烧网络的构建和燃烧行为

IF 3.3 Q2 CHEMISTRY, MULTIDISCIPLINARY Energetic Materials Frontiers Pub Date : 2024-09-01 DOI:10.1016/j.enmf.2024.08.005
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引用次数: 0

摘要

为了突破传统柱状材料带来的自上而下的燃烧模式,探索在二维维度上进行延迟成分阵列构建的探索。本研究借助微型笔式直接墨水书写装置,将上述材料分散在DMF中,以硼和金属氧化物为电荷主体,以F为粘结剂,制备了具有良好成型性能的B-CuO、B-BiO、B-FeO棒和燃烧网络。用镍铬丝对小棒进行热点燃,并用高速摄像机跟踪不同配方、间距和高度的小棒的火焰传播行为,在不蹿火的前提下设计了一系列燃烧网络。结果表明,在当量比为 1.0-4.0 时,B-CuO 棒的点火速度水平最快(19.71-29.02 mm -s),其次是 B-BiO(5.99-16.01 mm -s),B-FeO 最慢(1.91-4.94 mm -s)。在当量比为 1.0-1.5 时,木棒的燃烧效果最好。选择 B-CuO、B-BiO 和 B-FeO,在等效比分别为 1.0、1.5 和 1.5 时,在 50 × 50 毫米的玻璃片上构建了多种燃烧网络,其中 B-CuO 的燃烧时间最短(5.17 秒),燃烧网络总长度最短(252 毫米),B-BiO 可实现 400 毫米的网络。而 B-FeO 可以实现 608 毫米的网络长度和 130.7 秒的燃烧时间。通过这些研究,实现了硼金属氧化物的二维燃烧网络构建,为小尺寸延迟作用提供了新思路。
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Construction and combustion behavior of horizontal two-dimension combustion networks of boron-metal oxides
In order to break through the top-down combustion mode brought by the traditional pillars, it is explored to explore the exploration of delay composition array construction in two-dimensional dimensions. In this study, B-CuO, B-Bi2O3, B-Fe2O3 sticks and combustion networks with good forming properties were prepared with the help of a micro-pen direct ink writing device by dispersing the above materials in DMF with boron and metal oxides as the main body of the charge and F2602 as the binder. The sticks were thermally ignited using a nichrome wire, and the flame propagation behaviors of the sticks with different formulations, spacings and heights were tracked with a high-speed camera, and a series of combustion networks were designed on the premise of not leaping into flames. Results show that the B-CuO stick has the fastest ignition speed level (19.71–29.02 mm ·s−1) at equivalence ratios of 1.0–4.0, followed by B-Bi2O3 (5.99–16.01 mm ·s−1) and B-Fe2O3 is the slowest (1.91–4.94 mm ·s−1). The sticks burned best at an equivalence ratio of 1.0–1.5. A variety of combustion networks were constructed on 50 × 50 mm glass slides by selecting B-CuO, B-Bi2O3, and B-Fe2O3 at the equivalence ratios of 1.0, 1.5, and 1.5, respectively, among which B-CuO had the shortest combustion time (5.17 s), the shortest total combustion network length (252 mm), and 400 mm network could be realized for B-Bi2O3. Construction and 19.85 s, and B-Fe2O3 can realize 608 mm network length and 130.7 s combustion time. Through these studies, the two-dimensional combustion network construction of boron-metal oxides was realized, which provides a new idea for the delay action in small size.
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来源期刊
Energetic Materials Frontiers
Energetic Materials Frontiers Materials Science-Materials Science (miscellaneous)
CiteScore
6.90
自引率
0.00%
发文量
42
审稿时长
12 weeks
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