Qiang Peng, Rongqiu Li, Sijie Yin, Qiaolin Tang, Rong Sun, Guanjun Chang, Ming Kang
{"title":"水热降解:评估聚(乳酸)生物降解性能的新型快速方法","authors":"Qiang Peng, Rongqiu Li, Sijie Yin, Qiaolin Tang, Rong Sun, Guanjun Chang, Ming Kang","doi":"10.1134/S156009042460089X","DOIUrl":null,"url":null,"abstract":"<p>In order to evaluate the bio-degradation performance of different kinds of poly(lactic acid) (PLA) rapidly, a new method, called hydro-thermal degradation was developed. Four kinds of commercial grade PLA were analyzed by both bio-degradation and hydro-thermal degradation with their degradation performance investigated via weight loss (%), infrared spectra (IR), size-exclusion chromatography (SEC), and X‑ray diffraction measurements (XRD). The experimental results showed that the bio-degradation performance, which would take several years to degrade totally, could degrade in a short time (2 h) at 170°C by the hydro-thermal degradation. The order of the degradation rate is Revode101 > Revode210 > Revode190 > Revode290, corresponding with the structure characteristics of them. Thus, this new method provides a simple and effective way to degrade the PLA rapidly and to evaluate its bio-degradation performance.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"66 3","pages":"338 - 348"},"PeriodicalIF":1.0000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydro-Thermal Degradation: A New and Rapid Method for Evaluating the Bio-degradation Performance of Poly(lactic acid)\",\"authors\":\"Qiang Peng, Rongqiu Li, Sijie Yin, Qiaolin Tang, Rong Sun, Guanjun Chang, Ming Kang\",\"doi\":\"10.1134/S156009042460089X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In order to evaluate the bio-degradation performance of different kinds of poly(lactic acid) (PLA) rapidly, a new method, called hydro-thermal degradation was developed. Four kinds of commercial grade PLA were analyzed by both bio-degradation and hydro-thermal degradation with their degradation performance investigated via weight loss (%), infrared spectra (IR), size-exclusion chromatography (SEC), and X‑ray diffraction measurements (XRD). The experimental results showed that the bio-degradation performance, which would take several years to degrade totally, could degrade in a short time (2 h) at 170°C by the hydro-thermal degradation. The order of the degradation rate is Revode101 > Revode210 > Revode190 > Revode290, corresponding with the structure characteristics of them. Thus, this new method provides a simple and effective way to degrade the PLA rapidly and to evaluate its bio-degradation performance.</p>\",\"PeriodicalId\":739,\"journal\":{\"name\":\"Polymer Science, Series B\",\"volume\":\"66 3\",\"pages\":\"338 - 348\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series B\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S156009042460089X\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S156009042460089X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Hydro-Thermal Degradation: A New and Rapid Method for Evaluating the Bio-degradation Performance of Poly(lactic acid)
In order to evaluate the bio-degradation performance of different kinds of poly(lactic acid) (PLA) rapidly, a new method, called hydro-thermal degradation was developed. Four kinds of commercial grade PLA were analyzed by both bio-degradation and hydro-thermal degradation with their degradation performance investigated via weight loss (%), infrared spectra (IR), size-exclusion chromatography (SEC), and X‑ray diffraction measurements (XRD). The experimental results showed that the bio-degradation performance, which would take several years to degrade totally, could degrade in a short time (2 h) at 170°C by the hydro-thermal degradation. The order of the degradation rate is Revode101 > Revode210 > Revode190 > Revode290, corresponding with the structure characteristics of them. Thus, this new method provides a simple and effective way to degrade the PLA rapidly and to evaluate its bio-degradation performance.
期刊介绍:
Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed