M. G. Shaibakova, E. I. Titova, L. K. Dil’mukhametova, I. R. Ramazanov
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Titanocene-catalyzed selective synthesis of 2,4-dialkyl-6-(2-methoxyethyl)pyridines by the reaction of terminal acetylenes with 3-methoxypropionitrile
A selective one-pot method was developed for the synthesis of 2,4-dialkyl-6-(2-methoxyethyl)pyridines in yields of 70–82% by the reaction of terminal acetylenes with 3-methoxypropionitrile in the presence of EtAlCl2, Mg, and Cp2TiCl2 (10 mol.%).
期刊介绍:
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.