硼酸和三乙醇胺化合物对磷酸镁钾水泥早期水化性能的影响

IF 7.4 1区 工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Construction and Building Materials Pub Date : 2024-09-19 DOI:10.1016/j.conbuildmat.2024.138364
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引用次数: 0

摘要

为了提高磷酸二氢钾镁水泥(MKPC)的早期性能,并弥补因添加硼酸(BA)而造成的抗压强度降低,本研究中加入了三乙醇胺(TEA)。这项研究证明,三乙醇胺阻碍了氧化镁的溶解,并与钾离子形成了复合物,这一点在抗压强度、水化热分析、微观结构分析、电导率和离子浓度等测试中都得到了证明。此外,研究还表明,在 MKPC 中添加 2 wt% 的 BA 和 2 wt% 的三乙醇胺可显著改善其特性,而对其早期抗压强度的影响却很小。研究发现,该化合物可将凝结时间和流动性分别延长 200 % 和 32 %,同时还能抑制 K 型石英岩的形成。MKPC 的水化产物类型没有发生变化,24 小时后的早期抗压强度可达 42.52 兆帕,仅略微降低了 1.78%。
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Effect of boric acid and triethanolamine compound on early hydration properties of magnesium potassium phosphate cement

To enhance the early performance of magnesium potassium phosphate cement (MKPC) and compensate for loose of compressive strength caused by the addition of boric acid (BA), triethanolamine (TEA) was incorporated in this work. This research was demonstrated that TEA hindered the dissolution of MgO and formed a complex with potassium ions, as evidenced by tests including compressive strength, hydration heat analysis, microstructure analysis, conductivity, and ion concentration. Furthermore, the study demonstrated that the addition of 2 wt% BA and 2 wt% TEA to MKPC resulted in a significant improvement in its characteristics, while only minimally affecting its early compressive strength. The compound was found to extend the setting time and enhance fluidity by 200 % and 32 % respectively, while also inhibiting the formation of K-type struvite. The hydration product type of MKPC did not change, and MKPC can reach an early compressive strength of 42.52 MPa at 24 h, only experiencing a slight reduction of 1.78 %.

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来源期刊
Construction and Building Materials
Construction and Building Materials 工程技术-材料科学:综合
CiteScore
13.80
自引率
21.60%
发文量
3632
审稿时长
82 days
期刊介绍: Construction and Building Materials offers an international platform for sharing innovative and original research and development in the realm of construction and building materials, along with their practical applications in new projects and repair practices. The journal publishes a diverse array of pioneering research and application papers, detailing laboratory investigations and, to a limited extent, numerical analyses or reports on full-scale projects. Multi-part papers are discouraged. Additionally, Construction and Building Materials features comprehensive case studies and insightful review articles that contribute to new insights in the field. Our focus is on papers related to construction materials, excluding those on structural engineering, geotechnics, and unbound highway layers. Covered materials and technologies encompass cement, concrete reinforcement, bricks and mortars, additives, corrosion technology, ceramics, timber, steel, polymers, glass fibers, recycled materials, bamboo, rammed earth, non-conventional building materials, bituminous materials, and applications in railway materials.
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