Lihua Fu , Meng Zhou , Yuanan Gao , Bin Gan , Sanming Du , Yongzhen Zhang , Chenfei Song , Lvdong Hua , Guofeng Zhang
{"title":"含有不同尺寸 Cr3C2 颗粒的热压烧结 Cr3C2/Ni3Al 复合材料的微观结构、硬度和磨损性能","authors":"Lihua Fu , Meng Zhou , Yuanan Gao , Bin Gan , Sanming Du , Yongzhen Zhang , Chenfei Song , Lvdong Hua , Guofeng Zhang","doi":"10.1016/j.intermet.2024.108503","DOIUrl":null,"url":null,"abstract":"<div><p>In this study, Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites containing Cr<sub>3</sub>C<sub>2</sub> particles of different sizes were prepared via hot-press sintering. Subsequently, the effects of the size of the added Cr<sub>3</sub>C<sub>2</sub> particles on the microstructure, hardness, and tribological properties of the Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites were investigated. The results showed that the Ni<sub>3</sub>Al powder and Cr<sub>3</sub>C<sub>2</sub> particles in the composites exhibited obvious interdiffusion interactions during the hot-press sintering process and formed a new diffusion phase with an M<sub>7</sub>C<sub>3</sub> (M = Cr, Fe, and Ni) structure in the Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites. In addition, the diffusion effect in the composites with small Cr<sub>3</sub>C<sub>2</sub> particles was full, the proportion of the M<sub>7</sub>C<sub>3</sub> (M = Cr, Fe, and Ni) diffusion phase in the composites was greater, and the solid-solution strengthening effect of the matrix phase was evident. The hardness of the Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites was noticeably higher than that of the Ni<sub>3</sub>Al alloy because of the combination of particle, solid-solution, and refined crystalline strengthening effects. The composite with 5 μm Cr<sub>3</sub>C<sub>2</sub> particles displayed the maximum hardness (56.3 HRC) and best wear resistance. The wear mechanism results indicated that the carbide particles in the composites improved the hardness, carried the load, and blocked the movement of abrasive particles, effectively protecting the matrix from wear. However, when the added Cr<sub>3</sub>C<sub>2</sub> particles were too large, the weak interfacial bond between the chromium carbides and the matrix phases in the composites allowed the chromium carbides to easily crack and fall off, which decreased the wear resistance.</p></div>","PeriodicalId":331,"journal":{"name":"Intermetallics","volume":"175 ","pages":"Article 108503"},"PeriodicalIF":4.3000,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructure, hardness, and wear properties of hot-press sintered Cr3C2/Ni3Al composites containing Cr3C2 particles of different sizes\",\"authors\":\"Lihua Fu , Meng Zhou , Yuanan Gao , Bin Gan , Sanming Du , Yongzhen Zhang , Chenfei Song , Lvdong Hua , Guofeng Zhang\",\"doi\":\"10.1016/j.intermet.2024.108503\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this study, Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites containing Cr<sub>3</sub>C<sub>2</sub> particles of different sizes were prepared via hot-press sintering. Subsequently, the effects of the size of the added Cr<sub>3</sub>C<sub>2</sub> particles on the microstructure, hardness, and tribological properties of the Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites were investigated. The results showed that the Ni<sub>3</sub>Al powder and Cr<sub>3</sub>C<sub>2</sub> particles in the composites exhibited obvious interdiffusion interactions during the hot-press sintering process and formed a new diffusion phase with an M<sub>7</sub>C<sub>3</sub> (M = Cr, Fe, and Ni) structure in the Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites. In addition, the diffusion effect in the composites with small Cr<sub>3</sub>C<sub>2</sub> particles was full, the proportion of the M<sub>7</sub>C<sub>3</sub> (M = Cr, Fe, and Ni) diffusion phase in the composites was greater, and the solid-solution strengthening effect of the matrix phase was evident. The hardness of the Cr<sub>3</sub>C<sub>2</sub>/Ni<sub>3</sub>Al composites was noticeably higher than that of the Ni<sub>3</sub>Al alloy because of the combination of particle, solid-solution, and refined crystalline strengthening effects. The composite with 5 μm Cr<sub>3</sub>C<sub>2</sub> particles displayed the maximum hardness (56.3 HRC) and best wear resistance. The wear mechanism results indicated that the carbide particles in the composites improved the hardness, carried the load, and blocked the movement of abrasive particles, effectively protecting the matrix from wear. However, when the added Cr<sub>3</sub>C<sub>2</sub> particles were too large, the weak interfacial bond between the chromium carbides and the matrix phases in the composites allowed the chromium carbides to easily crack and fall off, which decreased the wear resistance.</p></div>\",\"PeriodicalId\":331,\"journal\":{\"name\":\"Intermetallics\",\"volume\":\"175 \",\"pages\":\"Article 108503\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-09-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Intermetallics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0966979524003224\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Intermetallics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0966979524003224","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Microstructure, hardness, and wear properties of hot-press sintered Cr3C2/Ni3Al composites containing Cr3C2 particles of different sizes
In this study, Cr3C2/Ni3Al composites containing Cr3C2 particles of different sizes were prepared via hot-press sintering. Subsequently, the effects of the size of the added Cr3C2 particles on the microstructure, hardness, and tribological properties of the Cr3C2/Ni3Al composites were investigated. The results showed that the Ni3Al powder and Cr3C2 particles in the composites exhibited obvious interdiffusion interactions during the hot-press sintering process and formed a new diffusion phase with an M7C3 (M = Cr, Fe, and Ni) structure in the Cr3C2/Ni3Al composites. In addition, the diffusion effect in the composites with small Cr3C2 particles was full, the proportion of the M7C3 (M = Cr, Fe, and Ni) diffusion phase in the composites was greater, and the solid-solution strengthening effect of the matrix phase was evident. The hardness of the Cr3C2/Ni3Al composites was noticeably higher than that of the Ni3Al alloy because of the combination of particle, solid-solution, and refined crystalline strengthening effects. The composite with 5 μm Cr3C2 particles displayed the maximum hardness (56.3 HRC) and best wear resistance. The wear mechanism results indicated that the carbide particles in the composites improved the hardness, carried the load, and blocked the movement of abrasive particles, effectively protecting the matrix from wear. However, when the added Cr3C2 particles were too large, the weak interfacial bond between the chromium carbides and the matrix phases in the composites allowed the chromium carbides to easily crack and fall off, which decreased the wear resistance.
期刊介绍：
This journal is a platform for publishing innovative research and overviews for advancing our understanding of the structure, property, and functionality of complex metallic alloys, including intermetallics, metallic glasses, and high entropy alloys.
The journal reports the science and engineering of metallic materials in the following aspects:
Theories and experiments which address the relationship between property and structure in all length scales.
Physical modeling and numerical simulations which provide a comprehensive understanding of experimental observations.
Stimulated methodologies to characterize the structure and chemistry of materials that correlate the properties.
Technological applications resulting from the understanding of property-structure relationship in materials.
Novel and cutting-edge results warranting rapid communication.
The journal also publishes special issues on selected topics and overviews by invitation only.
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