{"title":"金属离子驱动的 2H-硅烷化物和-锗化物的形成。","authors":"Chenghuan Liu , Marc Schmidtmann , Thomas Müller","doi":"10.1039/d4cc03984j","DOIUrl":null,"url":null,"abstract":"<div><div>The synthesis of potassio-1<em>H</em>-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2<em>H</em>-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 80","pages":"Pages 11295-11298"},"PeriodicalIF":4.2000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/cc/d4cc03984j?page=search","citationCount":"0","resultStr":"{\"title\":\"Metal ion-driven formation of 2H-silolides and -germolides†‡\",\"authors\":\"Chenghuan Liu , Marc Schmidtmann , Thomas Müller\",\"doi\":\"10.1039/d4cc03984j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The synthesis of potassio-1<em>H</em>-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2<em>H</em>-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"60 80\",\"pages\":\"Pages 11295-11298\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-09-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.rsc.org/en/content/articlepdf/2024/cc/d4cc03984j?page=search\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734524018986\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/8/30 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524018986","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/8/30 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Metal ion-driven formation of 2H-silolides and -germolides†‡
The synthesis of potassio-1H-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2H-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.
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