基于Fe3O4@coPPy-PTH纳米复合材料的磁性固相萃取技术,用于用微样品进样系统-火焰原子吸收光谱法测定酒精饮料和非酒精饮料中的钴、铬和镍。

IF 1.3 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Turkish Journal of Chemistry Pub Date : 2024-07-14 eCollection Date: 2024-01-01 DOI:10.55730/1300-0527.3683
Melike Küçüksakalli, Qamar Salamat, Buket Tireli, Şükrü Gökhan Elçi
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引用次数: 0

摘要

以噻吩和吡咯为原料,通过原位氧化聚合制备了一种新型的Fe3O4@coPPy-PTH纳米复合吸附剂。合成的纳米复合材料在不使用螯合剂的情况下灵敏地萃取和测定了金属离子钴(II)、铬(III)和镍(II),然后通过微量样品进样系统-火焰原子吸收光谱法进行了测定。扫描电子显微镜(SEM)和傅立叶变换红外光谱等先进的光谱和成像技术用于表征 Fe3O4@coPPy-PTH 纳米复合材料的组成和形态。扫描电镜观察结果表明,共聚物(PPy-PTH)涂层后,Fe3O4 纳米粒子的直径从 30 纳米变为 120 纳米。Fe3O4@coPPy-PTH纳米复合材料在强酸溶液中具有良好的分散性和稳定性。为了有效萃取所研究的分析物,对样品的 pH 值、样品溶液和洗脱液的体积、吸附剂的用量以及共存金属离子的干扰等因素进行了优化。在最佳条件下,所有分析物的预浓缩因子均为 25。校准曲线在 0.0-10.0 μg L-1 范围内呈线性关系,所有三种分析物的测定系数 (R2) 均大于 0.9957。计算得出的检测限(S/N = 3)范围为 0.17-0.23 μg L-1。以相对标准偏差表示的精密度值低于 3.0%,相对回收率在 88.6%-103.6% 之间。所提出的方法(Fe3O4@coPPy-PTH/MSPE/MIS-FAAS)成功地应用于啤酒、葡萄酒和非酒精饮料样品中金属离子的提取和测定。
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Magnetic solid-phase extraction technique based on Fe3O4@coPPy-PTH nanocomposite for extraction of cobalt, chromium, and nickel prior to determination by microsample injection system-flame atomic absorption spectrometry in alcoholic and nonalcoholic beverages.

A novel Fe3O4@coPPy-PTH nanocomposite-based sorbent was prepared via in situ oxidative polymerization using Fe3O4 nanoparticles with spherical and flower-like morphologies of thiophene and pyrrole as the feedstocks. The synthesized nanocomposite displayed sensitive extraction and determination of metal ions Co(II), Cr(III), and Ni(II) without a chelating agent, followed by microsample injection system-flame atomic absorption spectrometry. Advanced spectroscopic and imaging techniques including scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy were used to characterize the composition and morphology of the Fe3O4@coPPy-PTH nanocomposite. SEM observations showed that the size of the Fe3O4 nanoparticles changed from 30 nm to 120 nm in diameter after copolymer (PPy-PTH) coating. The Fe3O4@coPPy-PTH nanocomposite has good dispersion properties and stability in strong acid solutions. For effective extraction of the studied analytes, the influence of sample pH, volume of sample solution and eluent, amount of adsorbent, and interference of coexisting metal ions were optimized. Under the optimum conditions, preconcentration factors were obtained as 25 for all analytes. The calibration curves were linear in the range of 0.0-10.0 μg L-1 with coefficients of determination (R2) greater than 0.9957 for all three analytes. Limits of detection (S/N = 3) were calculated in the range of 0.17-0.23 μg L-1. Precision values, expressed as relative standard deviations, were lower than 3.0%, and relative recoveries were obtained in the range of 88.6%-103.6%. The proposed method (Fe3O4@coPPy-PTH/MSPE/MIS-FAAS) was successfully applied to extract and determine the studied metal ions in beer, wine, and nonalcoholic beverage samples.

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来源期刊
Turkish Journal of Chemistry
Turkish Journal of Chemistry 化学-工程:化工
CiteScore
2.40
自引率
7.10%
发文量
87
审稿时长
3 months
期刊介绍: The Turkish Journal of Chemistry is a bimonthly multidisciplinary journal published by the Scientific and Technological Research Council of Turkey (TÜBİTAK). The journal is dedicated to dissemination of knowledge in all disciplines of chemistry (organic, inorganic, physical, polymeric, technical, theoretical and analytical chemistry) as well as research at the interface with other sciences especially in chemical engineering where molecular aspects are key to the findings. The journal accepts English-language original manuscripts and contribution is open to researchers of all nationalities. The journal publishes refereed original papers, reviews, letters to editor and issues devoted to special fields. All manuscripts are peer-reviewed and electronic processing ensures accurate reproduction of text and data, plus publication times as short as possible.
期刊最新文献
Corrigendum to "Polybrominated methoxy- and hydroxynaphthalenes" [Turkish Journal of Chemistry 40 (2) 2016 332-346 ]. Synthesis and characterization of new hexahydroquinoline derivatives and evaluation of their cytotoxicity, intracellular ROS production, and inhibitory effects on inflammatory mediators. Identification of blood at simulated crime scenes using silver nanoparticles with SERS. Magnetic solid-phase extraction technique based on Fe3O4@coPPy-PTH nanocomposite for extraction of cobalt, chromium, and nickel prior to determination by microsample injection system-flame atomic absorption spectrometry in alcoholic and nonalcoholic beverages. Synthesis of 3-methyl-3-buten-1-ol by supercritical CO2 in coordination with HZSM-5-catalyzed formaldehyde-isobutene Prins reaction.
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