Fan Xiao, Wei Wang, Longxin Chen, Kai Li, Yuntong Ge, Jionghao Li
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Investigation on the Adhesion Force between Tetrabutylammonium Bromide Hydrate Particles Using Atomic Force Microscopy.
This work investigates the adhesion force between tetrabutylammonium bromide (TBAB) hydrate particles dispersed in decane at different temperatures and TBAB concentrations using an atomic force microscopy. The thickness of the quasi-liquid layer (QLL) on the surface of the hydrate particles is calculated based on an adhesion force model. The results of force measurements indicate that the adhesion force between the hydrate particles increases with increasing temperature when TBAB concentration is 30 wt %. The increment of adhesion force between particles could be due to the increase in the QLL thickness on the particle surfaces. Furthermore, the force results also reveal that the adhesion force between hydrate particles(ice) at 253 K decreases when TBAB concentration increases from 0 to 30 wt %. The calculation indicates that QLL on the surface of formed hydrate particles becomes thinner at higher TBAB concentrations, which could be due to the conversion rate of water to hydrate within particles. The thickness of QLL is directly influenced by the temperature and TBAB concentration, which contributes to the adhesion force between hydrate particles.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).