{"title":"基于配位相互作用的高比表面积自组装荧光 Zn-MOF,用于灵敏检测和选择性去除水中的四环素类抗生素","authors":"","doi":"10.1016/j.optmat.2024.116126","DOIUrl":null,"url":null,"abstract":"<div><div>As one of most common used antibiotics, tetracyclines (TCs) have been widespread used in many fields. However, the abuse of antibiotics resulted in serious environmental pollutants. Therefore, it is of great significance to develop new materials for rapid detection and effective removal of tetracyclines. In this study, a step-by-step synthesis strategy was adopted to prepare a fluorescent LMOF material Znq<sub>2</sub>@ZIF-8, and it was well characterized. Znq<sub>2</sub>@ZIF-8 showed strong green emission and has large specific surface area, with excellent stability and good recyclability. The fluorescence of Znq<sub>2</sub>@ZIF-8 can be quenched with the addition of tetracycline (TC) in the aqueous environment, demonstrating good selectivity and strong interference resistance, with a limit of detection (LOD) of 0.13 μmol∙L<sup>−1</sup>. In addition, Znq<sub>2</sub>@ZIF-8 exhibits excellent adsorption and removal abilities for TC. As a result, Znq<sub>2</sub>@ZIF-8 enables the simultaneous detection and removal of TC in aqueous environments, providing a solution for future TC pollution in water.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Self-assembled fluorescent Zn-MOF with high specific surface area based on the coordination interaction for sensitive detection and selective removal of tetracycline antibiotic in water\",\"authors\":\"\",\"doi\":\"10.1016/j.optmat.2024.116126\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>As one of most common used antibiotics, tetracyclines (TCs) have been widespread used in many fields. However, the abuse of antibiotics resulted in serious environmental pollutants. Therefore, it is of great significance to develop new materials for rapid detection and effective removal of tetracyclines. In this study, a step-by-step synthesis strategy was adopted to prepare a fluorescent LMOF material Znq<sub>2</sub>@ZIF-8, and it was well characterized. Znq<sub>2</sub>@ZIF-8 showed strong green emission and has large specific surface area, with excellent stability and good recyclability. The fluorescence of Znq<sub>2</sub>@ZIF-8 can be quenched with the addition of tetracycline (TC) in the aqueous environment, demonstrating good selectivity and strong interference resistance, with a limit of detection (LOD) of 0.13 μmol∙L<sup>−1</sup>. In addition, Znq<sub>2</sub>@ZIF-8 exhibits excellent adsorption and removal abilities for TC. As a result, Znq<sub>2</sub>@ZIF-8 enables the simultaneous detection and removal of TC in aqueous environments, providing a solution for future TC pollution in water.</div></div>\",\"PeriodicalId\":19564,\"journal\":{\"name\":\"Optical Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-09-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optical Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0925346724013090\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925346724013090","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Self-assembled fluorescent Zn-MOF with high specific surface area based on the coordination interaction for sensitive detection and selective removal of tetracycline antibiotic in water
As one of most common used antibiotics, tetracyclines (TCs) have been widespread used in many fields. However, the abuse of antibiotics resulted in serious environmental pollutants. Therefore, it is of great significance to develop new materials for rapid detection and effective removal of tetracyclines. In this study, a step-by-step synthesis strategy was adopted to prepare a fluorescent LMOF material Znq2@ZIF-8, and it was well characterized. Znq2@ZIF-8 showed strong green emission and has large specific surface area, with excellent stability and good recyclability. The fluorescence of Znq2@ZIF-8 can be quenched with the addition of tetracycline (TC) in the aqueous environment, demonstrating good selectivity and strong interference resistance, with a limit of detection (LOD) of 0.13 μmol∙L−1. In addition, Znq2@ZIF-8 exhibits excellent adsorption and removal abilities for TC. As a result, Znq2@ZIF-8 enables the simultaneous detection and removal of TC in aqueous environments, providing a solution for future TC pollution in water.
期刊介绍:
Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials.
OPTICAL MATERIALS focuses on:
• Optical Properties of Material Systems;
• The Materials Aspects of Optical Phenomena;
• The Materials Aspects of Devices and Applications.
Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.