Ondřej Jankovský , Zbyšek Pavlík , Martina Záleská , Milena Pavlíková , Adam Pivák , Jana Nábělková , Anna-Marie Lauermannová , Adéla Jiříčková , David Sedmidubský
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引用次数: 0
摘要
水泥是最主要的建筑粘结剂,其生产与高能耗、巨大的原材料损耗和大量的二氧化碳排放有关,使水泥成为污染最严重的材料之一。本研究旨在通过大幅降低砂浆成分中硅酸盐水泥(PC)的比例,为建筑行业的可持续发展做出贡献。通过添加大量褐煤燃烧产生的粉煤灰掺合料(FA)来降低粘结剂含量,同时研究粉煤灰掺合料中的重金属(HMs)在 PC/FA 基质中的固定效果。在分析 FA 掺量对所制备砂浆性能的影响的同时,还重点研究了长期固化对砂浆物理参数发展和 HMs 固定化效率的影响。研究结果表明,在 PC 中添加高达 20 wt%的 FA,可生产出高强度、低孔隙率的建筑砂浆,同时将有害物质(如 HMs)限制在基质中。在相对湿度较高的条件下长期固化可使砂浆结构不断演变和固化,从而提高其工程特性和固定 HMs 的效率。
Fly ash admixture originating from lignite combustion in construction mortars – Time evolution of technical parameters and heavy metals leachability
The production of cement, the predominant construction binder, is associated with high energy consumption, enormous raw material depletion, and a large volume of CO2 emissions, making cement one of the most polluting materials. This study aims to contribute to the sustainability of the construction industry by significantly reducing the proportion of Portland cement (PC) in the composition of mortars. The binder content reduction was achieved by the addition of large amounts of fly ash admixture (FA) from lignite combustion while studying the effectiveness of the immobilization of heavy metals (HMs), which are present in FA, in the PC/FA matrix. Along with the analysis of the FA admixture amount on the properties of the prepared mortars, emphasis was put on the study of the influence of prolonged curing on the development of the physical parameters of the mortars and the immobilization efficiency of the HMs. It was revealed that FA can be added to PC by up to 20 wt%, enabling the production of construction mortars with high strength and low porosity, while confining hazardous substances such as HMs in the matrix. Prolonged curing at elevated relative humidity led to the continuous evolution and solidification of the mortar structure, improving its engineering properties and HMs immobilization efficiency.