{"title":"金修饰金属有机框架光子异质结构作为 SERS 传感器,用于富集和检测痕量有机染料和农药","authors":"","doi":"10.1016/j.snb.2024.136684","DOIUrl":null,"url":null,"abstract":"<div><div>Surface enhanced Raman scattering (SERS) sensors with excellent sensitivity, stability and repeatability are essential for the ultrasensitive analysis of trace targets. In this study, a SERS sensor was developed using a photonic heterostructure composed of Au nanoparticles (AuNPs) & Zeolitic Imidazolate Framework-8 photonic crystals (ZIF-8 PCs). The sensor aims to enrich and detect organic dyes and pesticides, with enhanced detection capabilities achieved through adjustments in AuNPs content and the band-edge effects of ZIF-8 PCs. The sensor exhibited excellent performances in detecting 4-mercaptobenzoic acid. The detection limit was 1 × 10<sup>–12</sup> mol·L<sup>−1</sup>, with a relative standard deviation of 5.0 % and the enhancement factor of 1.439 × 10<sup>11</sup>. Furthermore, the self-enrichment function of the sensor was verified through molecular dynamics simulations. This validation enabled the SERS sensor to be effectively utilized for the analysis of Rhodamine 6 G (R6G), methylene blue (MB), Thiabendazole (TBZ) and Parathion-methyl (PTM) without complex pretreatment. The detection limits achieved were 1 × 10<sup>–12</sup> for R6G and MB, and 1 × 10<sup>–11</sup> mol·L<sup>−1</sup> for TBZ and PTM, respectively. This study presented an effective strategy for constructing high-performance SERS sensors, elucidated the mechanism of analyte enrichment and achieved the detection of samples in natural lake water, which offers a new option for on-site monitoring of contaminants with a portable Raman spectroscopy.</div></div>","PeriodicalId":425,"journal":{"name":"Sensors and Actuators B: Chemical","volume":null,"pages":null},"PeriodicalIF":8.0000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Au-modified metal-organic framework photonic heterostructure as a SERS sensor for enrichment and detection of trace organic dyes and pesticides\",\"authors\":\"\",\"doi\":\"10.1016/j.snb.2024.136684\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Surface enhanced Raman scattering (SERS) sensors with excellent sensitivity, stability and repeatability are essential for the ultrasensitive analysis of trace targets. In this study, a SERS sensor was developed using a photonic heterostructure composed of Au nanoparticles (AuNPs) & Zeolitic Imidazolate Framework-8 photonic crystals (ZIF-8 PCs). The sensor aims to enrich and detect organic dyes and pesticides, with enhanced detection capabilities achieved through adjustments in AuNPs content and the band-edge effects of ZIF-8 PCs. The sensor exhibited excellent performances in detecting 4-mercaptobenzoic acid. The detection limit was 1 × 10<sup>–12</sup> mol·L<sup>−1</sup>, with a relative standard deviation of 5.0 % and the enhancement factor of 1.439 × 10<sup>11</sup>. Furthermore, the self-enrichment function of the sensor was verified through molecular dynamics simulations. This validation enabled the SERS sensor to be effectively utilized for the analysis of Rhodamine 6 G (R6G), methylene blue (MB), Thiabendazole (TBZ) and Parathion-methyl (PTM) without complex pretreatment. The detection limits achieved were 1 × 10<sup>–12</sup> for R6G and MB, and 1 × 10<sup>–11</sup> mol·L<sup>−1</sup> for TBZ and PTM, respectively. This study presented an effective strategy for constructing high-performance SERS sensors, elucidated the mechanism of analyte enrichment and achieved the detection of samples in natural lake water, which offers a new option for on-site monitoring of contaminants with a portable Raman spectroscopy.</div></div>\",\"PeriodicalId\":425,\"journal\":{\"name\":\"Sensors and Actuators B: Chemical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.0000,\"publicationDate\":\"2024-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sensors and Actuators B: Chemical\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S092540052401414X\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ANALYTICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sensors and Actuators B: Chemical","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S092540052401414X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
Au-modified metal-organic framework photonic heterostructure as a SERS sensor for enrichment and detection of trace organic dyes and pesticides
Surface enhanced Raman scattering (SERS) sensors with excellent sensitivity, stability and repeatability are essential for the ultrasensitive analysis of trace targets. In this study, a SERS sensor was developed using a photonic heterostructure composed of Au nanoparticles (AuNPs) & Zeolitic Imidazolate Framework-8 photonic crystals (ZIF-8 PCs). The sensor aims to enrich and detect organic dyes and pesticides, with enhanced detection capabilities achieved through adjustments in AuNPs content and the band-edge effects of ZIF-8 PCs. The sensor exhibited excellent performances in detecting 4-mercaptobenzoic acid. The detection limit was 1 × 10–12 mol·L−1, with a relative standard deviation of 5.0 % and the enhancement factor of 1.439 × 1011. Furthermore, the self-enrichment function of the sensor was verified through molecular dynamics simulations. This validation enabled the SERS sensor to be effectively utilized for the analysis of Rhodamine 6 G (R6G), methylene blue (MB), Thiabendazole (TBZ) and Parathion-methyl (PTM) without complex pretreatment. The detection limits achieved were 1 × 10–12 for R6G and MB, and 1 × 10–11 mol·L−1 for TBZ and PTM, respectively. This study presented an effective strategy for constructing high-performance SERS sensors, elucidated the mechanism of analyte enrichment and achieved the detection of samples in natural lake water, which offers a new option for on-site monitoring of contaminants with a portable Raman spectroscopy.
期刊介绍:
Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.