光诱导电荷转移赋予 Ta4C3 和 Nb4C3 MXenes 高 SERS 性能

IF 3.7 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Langmuir Pub Date : 2024-09-25 DOI:10.1021/acs.langmuir.4c02165
Leilei Lan, Ziheng Ni, Caiye Zhao, Juan Gao, Xiao Tang, Zhongwei Qu, Lingcheng Zheng, Xingce Fan, Teng Qiu
{"title":"光诱导电荷转移赋予 Ta4C3 和 Nb4C3 MXenes 高 SERS 性能","authors":"Leilei Lan, Ziheng Ni, Caiye Zhao, Juan Gao, Xiao Tang, Zhongwei Qu, Lingcheng Zheng, Xingce Fan, Teng Qiu","doi":"10.1021/acs.langmuir.4c02165","DOIUrl":null,"url":null,"abstract":"This study introduces two-dimensional (2D) Ta<sub>4</sub>C<sub>3</sub> and Nb<sub>4</sub>C<sub>3</sub> MXenes as outstanding materials for surface-enhanced Raman scattering (SERS) sensing, marking a significant departure from traditional noble-metal substrates. These MXenes exhibit exceptional SERS capabilities, achieving enhancement factors around 10<sup>5</sup> and detection limits as low as 10<sup>–7</sup> M for various analytes, including environmental pollutants and drugs. The core of their SERS functionality is attributed to the robust interfacial photoinduced charge-transfer interactions between the MXenes and the adsorbed molecules. This deep insight not only advances our understanding of MXene materials in SERS applications but also opens new avenues for developing highly sensitive and selective SERS sensors. The potential of Ta<sub>4</sub>C<sub>3</sub> and Nb<sub>4</sub>C<sub>3</sub> MXenes to revolutionize SERS technology underscores their importance in environmental monitoring, food safety, and beyond.","PeriodicalId":50,"journal":{"name":"Langmuir","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photoinduced Charge Transfer Empowers Ta4C3 and Nb4C3 MXenes with High SERS Performance\",\"authors\":\"Leilei Lan, Ziheng Ni, Caiye Zhao, Juan Gao, Xiao Tang, Zhongwei Qu, Lingcheng Zheng, Xingce Fan, Teng Qiu\",\"doi\":\"10.1021/acs.langmuir.4c02165\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study introduces two-dimensional (2D) Ta<sub>4</sub>C<sub>3</sub> and Nb<sub>4</sub>C<sub>3</sub> MXenes as outstanding materials for surface-enhanced Raman scattering (SERS) sensing, marking a significant departure from traditional noble-metal substrates. These MXenes exhibit exceptional SERS capabilities, achieving enhancement factors around 10<sup>5</sup> and detection limits as low as 10<sup>–7</sup> M for various analytes, including environmental pollutants and drugs. The core of their SERS functionality is attributed to the robust interfacial photoinduced charge-transfer interactions between the MXenes and the adsorbed molecules. This deep insight not only advances our understanding of MXene materials in SERS applications but also opens new avenues for developing highly sensitive and selective SERS sensors. The potential of Ta<sub>4</sub>C<sub>3</sub> and Nb<sub>4</sub>C<sub>3</sub> MXenes to revolutionize SERS technology underscores their importance in environmental monitoring, food safety, and beyond.\",\"PeriodicalId\":50,\"journal\":{\"name\":\"Langmuir\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Langmuir\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.langmuir.4c02165\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.langmuir.4c02165","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

本研究介绍了二维(2D)Ta4C3 和 Nb4C3 MXenes,它们是表面增强拉曼散射(SERS)传感的杰出材料,标志着与传统贵金属基底的重大差异。这些 MXenes 具有卓越的 SERS 功能,对包括环境污染物和药物在内的各种分析物具有约 105 的增强因子和低至 10-7 M 的检测限。其 SERS 功能的核心归功于 MXenes 与吸附分子之间强大的界面光诱导电荷转移相互作用。这一深刻的见解不仅加深了我们对 MXene 材料在 SERS 应用中的理解,还为开发高灵敏度和高选择性的 SERS 传感器开辟了新的途径。Ta4C3 和 Nb4C3 MXenes 在革新 SERS 技术方面的潜力凸显了它们在环境监测、食品安全等方面的重要性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Photoinduced Charge Transfer Empowers Ta4C3 and Nb4C3 MXenes with High SERS Performance
This study introduces two-dimensional (2D) Ta4C3 and Nb4C3 MXenes as outstanding materials for surface-enhanced Raman scattering (SERS) sensing, marking a significant departure from traditional noble-metal substrates. These MXenes exhibit exceptional SERS capabilities, achieving enhancement factors around 105 and detection limits as low as 10–7 M for various analytes, including environmental pollutants and drugs. The core of their SERS functionality is attributed to the robust interfacial photoinduced charge-transfer interactions between the MXenes and the adsorbed molecules. This deep insight not only advances our understanding of MXene materials in SERS applications but also opens new avenues for developing highly sensitive and selective SERS sensors. The potential of Ta4C3 and Nb4C3 MXenes to revolutionize SERS technology underscores their importance in environmental monitoring, food safety, and beyond.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
期刊最新文献
In Situ Synthesis and Visualization of Membrane SNAP25 Nano-Organization Revealing the Interlayer Interaction Forces in 2D Graphene Materials by Graphene-Wrapped Nanoprobe Ultrahydrophilic Inorganic Nanosheet-Based Nanofiltration Membranes for High Efficiency Separations of Inorganic Salts and Organic Dyes Atomic Erosion Behavior and Influence Mechanism of (CoCrFeMn)1–xNix High-Entropy Alloy Coating on Fracturing Pump Valves During Stimulation Operation Durability Properties of Steel Textiles and Bonding Properties at the Interface of Steel Textiles with Reinforced Mortar-Reinforced Concrete Systems
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1