Lian Wu, Lu Wang, Yu-Lei Liu, Xiao-Na Zhao, Jun Ma
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VUV Activated Fe(VI) by Promoting the Generation of Intermediate Valent Iron and Hydroxyl Radicals
In this study, vacuum ultraviolet (VUV) was first proposed to activate ferrate (Fe(VI)) for degrading micropollutants (e.g., carbamazepine (CBZ)). Results indicated that VUV/Fe(VI) could significantly facilitate the CBZ degradation, and the removal efficiencies of VUV/Fe(VI) were 30.9–83.4% higher than those of Fe(VI) at pH = 7.0–9.0. Correspondingly, the degradation rate constants of VUV/Fe(VI) were 2.3–36.0-fold faster than those of Fe(VI). Free radical quenching and probe experiments revealed that the dominant active species of VUV/Fe(VI) were •OH and Fe(V)/Fe(IV), whose contribution ratios were 43.3 to 48.6% and 48.2 to 46.6%, respectively, at pH = 7.0–9.0. VUV combined with Fe(VI) not only effectively mitigated the weak oxidizing ability of Fe(VI) under alkaline conditions (especially pH = 9.0) but also attenuated the deteriorating effect of background constituents on Fe(VI). In different real waters (tap water, river water, WWTPs effluent), VUV/Fe(VI) retained a remarkably enhanced effect on CBZ degradation compared to Fe(VI). Moreover, VUV/Fe(VI) exhibited outstanding performance in the debasement of CBZ and sulfamethoxazole (SMX), as well as six other micropollutants, displaying broad-spectrum capability in degrading micropollutants. Overall, this study developed a novel oxidation process that was efficient and energy-saving for the rapid removal of micropollutants.
期刊介绍:
Environmental Science & Technology (ES&T) is a co-sponsored academic and technical magazine by the Hubei Provincial Environmental Protection Bureau and the Hubei Provincial Academy of Environmental Sciences.
Environmental Science & Technology (ES&T) holds the status of Chinese core journals, scientific papers source journals of China, Chinese Science Citation Database source journals, and Chinese Academic Journal Comprehensive Evaluation Database source journals. This publication focuses on the academic field of environmental protection, featuring articles related to environmental protection and technical advancements.