基于拓扑算法优化 PEMFC 阴极气体扩散层的孔隙率和渗透率

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-18 DOI:10.1016/j.ijoes.2024.100803
Minggang Zheng , Han Liang , Wenxie Bu , Cheng Qu , Xiaoxu Hu , Zhihu Zhang
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引用次数: 0

摘要

气体扩散层(GDL)是质子交换膜燃料电池(PEMFC)中的关键部件,对质量传输和电池整体性能有重大影响。由于蛇形流场的入口和出口之间存在明显的压力梯度和不均匀的质量传输,本研究提出设计具有浓度梯度的 GDL,以优化性能。利用拓扑优化算法,研究重点是增强质量传输特性和提高电池效率。优化过程将蛇形流场中的压力分布、氧气浓度和含水量作为边界条件。通过优化 GDL 不同区域的孔隙率和渗透率,该研究旨在增强 GDL 的质量传输能力。仿真结果表明,将孔隙率初始化为 1 的优化效果更佳,可显著提高质量传输和电池的整体性能。虽然增加渗透率有助于改善质量传输,但与孔隙率优化相比,其影响并不显著。因此,GDL 孔隙率被认为是提高电池性能的主要因素,而渗透性调整则起次要作用。
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Porosity and permeability optimization of PEMFC cathode gas diffusion layer based on topology algorithm
The gas diffusion layer (GDL) is a crucial component in proton exchange membrane fuel cells (PEMFCs), significantly affecting mass transport and overall cell performance. Due to the pronounced pressure gradients and uneven mass transfer between the inlet and outlet of the serpentine flow field, this study proposes the design of a GDL with a concentration gradient to optimize performance. Leveraging topological optimization algorithms, the research focuses on enhancing the mass transport properties and improving cell efficiency. The optimization process considers the pressure distribution, oxygen concentration, and water content within the serpentine flow field as boundary conditions. By optimizing the porosity and permeability of the GDL in different regions, the study aims to enhance the GDL's mass transport capabilities. Simulation results demonstrate that initializing the porosity at 1 provides superior optimization, significantly enhancing mass transfer and overall cell performance. Although increased permeability contributes to improved mass transport, its impact is less significant compared to porosity optimization. Therefore, GDL porosity is identified as the dominant factor in enhancing cell performance, while permeability adjustments play a secondary role.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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