手性铁催化剂引发的不对称自由基反应的最新进展

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-10-10 DOI:10.1039/d4cc03047h
Jun Zhang , Jie Wu
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引用次数: 0

摘要

过渡金属催化的不对称自由基反应为获得对映纯度高的手性有机分子提供了一个通用而有效的平台。鉴于铁是目前最丰富且毒性较低的过渡金属元素,铁催化剂的应用被认为是一种更具可持续性和吸引力的方法。在过去的十年中,已经取得了一些令人振奋的显著成就。本文旨在概述配体铁催化不对称自由基反应的进展,重点介绍反应机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Recent progress in asymmetric radical reactions enabled by chiral iron catalysts
Transition-metal-catalyzed radical asymmetric reactions offer a versatile and effective platform for accessing chiral organic molecules with high enantiopurity. Given that iron is the most abundant and less toxic transition metalic element available, the application of iron catalysts is considered to be a more sustainable and attractive approach. Over the last decade, several exciting and notable achievements have been witnessed. In this highlight, we aim to provide an overview of the progress in ligand-enabled iron-catalyzed asymmetric radical reactions, with an emphasis on the reaction mechanisms.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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