Danxing Yang, Wen Fang, Hao Zhang, Xueyuan Gu, Haiyi Chen, Haitao Sun, Jun Luo
{"title":"不同浸出条件下工业土壤中镍和镉的迁移和可用性:DGT 和 DIFS 模型的启示","authors":"Danxing Yang, Wen Fang, Hao Zhang, Xueyuan Gu, Haiyi Chen, Haitao Sun, Jun Luo","doi":"10.1016/j.jhazmat.2024.135863","DOIUrl":null,"url":null,"abstract":"Rainfall runoff can mobilize heavy metals in industrial soils, posing environmental risks. The mobility and distribution of heavy metals in different industrial soil layers are often overlooked. This study employed dynamic leaching experiments in layered soil columns with DGT (the diffusive gradients in thin films) measurements and DIFS (DGT-induced fluxes in soils and sediments) model to describe the migration, availability, and resupply ability of metals at different depths in surface and deep soil columns of industrial soils. Results showed significantly higher available concentrations (<em>C</em><sub>DGT</sub> and <em>C</em><sub>Soln</sub>) of Ni and Cd in surface soils compared to deep soils, likely due to the differences in soil physiochemical properties (contamination, pH, and soil texture). Continuous leaching promoted the migration of available Ni and Cd in surface soils. Maximum values of <em>R</em><sub>Ni</sub> (0.79–0.91) and <em>R</em><sub>Cd</sub> (0.75–0.80) were observed in the top layer (0–4<!-- --> <!-- -->cm) of the surface soil, consistent with the trends of <em>R</em><sub>Fe</sub>. Combined DGT and DIFS model analysis implied higher potential availability and resupply of Ni and Cd in surface soil columns. These findings highlight the importance of considering dynamic leaching effects on heavy metal transport, availability, and release in industrial soils.","PeriodicalId":361,"journal":{"name":"Journal of Hazardous Materials","volume":null,"pages":null},"PeriodicalIF":12.2000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Migration and Availability of Ni and Cd in Industrial Soils Under Different Leaching Conditions: Insights from DGT and DIFS Models\",\"authors\":\"Danxing Yang, Wen Fang, Hao Zhang, Xueyuan Gu, Haiyi Chen, Haitao Sun, Jun Luo\",\"doi\":\"10.1016/j.jhazmat.2024.135863\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Rainfall runoff can mobilize heavy metals in industrial soils, posing environmental risks. The mobility and distribution of heavy metals in different industrial soil layers are often overlooked. This study employed dynamic leaching experiments in layered soil columns with DGT (the diffusive gradients in thin films) measurements and DIFS (DGT-induced fluxes in soils and sediments) model to describe the migration, availability, and resupply ability of metals at different depths in surface and deep soil columns of industrial soils. Results showed significantly higher available concentrations (<em>C</em><sub>DGT</sub> and <em>C</em><sub>Soln</sub>) of Ni and Cd in surface soils compared to deep soils, likely due to the differences in soil physiochemical properties (contamination, pH, and soil texture). Continuous leaching promoted the migration of available Ni and Cd in surface soils. Maximum values of <em>R</em><sub>Ni</sub> (0.79–0.91) and <em>R</em><sub>Cd</sub> (0.75–0.80) were observed in the top layer (0–4<!-- --> <!-- -->cm) of the surface soil, consistent with the trends of <em>R</em><sub>Fe</sub>. Combined DGT and DIFS model analysis implied higher potential availability and resupply of Ni and Cd in surface soil columns. These findings highlight the importance of considering dynamic leaching effects on heavy metal transport, availability, and release in industrial soils.\",\"PeriodicalId\":361,\"journal\":{\"name\":\"Journal of Hazardous Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":12.2000,\"publicationDate\":\"2024-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Hazardous Materials\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jhazmat.2024.135863\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Hazardous Materials","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.jhazmat.2024.135863","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Migration and Availability of Ni and Cd in Industrial Soils Under Different Leaching Conditions: Insights from DGT and DIFS Models
Rainfall runoff can mobilize heavy metals in industrial soils, posing environmental risks. The mobility and distribution of heavy metals in different industrial soil layers are often overlooked. This study employed dynamic leaching experiments in layered soil columns with DGT (the diffusive gradients in thin films) measurements and DIFS (DGT-induced fluxes in soils and sediments) model to describe the migration, availability, and resupply ability of metals at different depths in surface and deep soil columns of industrial soils. Results showed significantly higher available concentrations (CDGT and CSoln) of Ni and Cd in surface soils compared to deep soils, likely due to the differences in soil physiochemical properties (contamination, pH, and soil texture). Continuous leaching promoted the migration of available Ni and Cd in surface soils. Maximum values of RNi (0.79–0.91) and RCd (0.75–0.80) were observed in the top layer (0–4 cm) of the surface soil, consistent with the trends of RFe. Combined DGT and DIFS model analysis implied higher potential availability and resupply of Ni and Cd in surface soil columns. These findings highlight the importance of considering dynamic leaching effects on heavy metal transport, availability, and release in industrial soils.
期刊介绍:
The Journal of Hazardous Materials serves as a global platform for promoting cutting-edge research in the field of Environmental Science and Engineering. Our publication features a wide range of articles, including full-length research papers, review articles, and perspectives, with the aim of enhancing our understanding of the dangers and risks associated with various materials concerning public health and the environment. It is important to note that the term "environmental contaminants" refers specifically to substances that pose hazardous effects through contamination, while excluding those that do not have such impacts on the environment or human health. Moreover, we emphasize the distinction between wastes and hazardous materials in order to provide further clarity on the scope of the journal. We have a keen interest in exploring specific compounds and microbial agents that have adverse effects on the environment.