Kristine L. Konkol, Wyatt D. Wilcox and Seth C. Rasmussen
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引用次数: 0
摘要
报告了一种新的双齿桥接配体--双(2-吡啶基)噻吩并[3,4-b]吡嗪，并以其单金属和双金属 Ru(II) 复合物为代表。报告对这些物质进行了光谱、电化学和 X 射线晶体学表征，双金属配合物的两个 Ru(III)/Ru(II) 偶联物的分离表明，金属与金属之间的交流比传统的多吡啶类似物更好。
2,3-Bis(2-pyridyl)thieno[3,4-b]pyrazine and its ruthenium(ii) complexes: a new bidentate bridging ligand for enhanced metal–metal communication†
A new bidentate bridging ligand, bis(2-pyridyl)thieno[3,4-b]pyrazine is reported, along with its mono- and bi-metallic Ru(II) complexes as representative examples. Spectroscopic, electrochemical and X-ray crystallographic characterization of these species is reported, with the separation of the two Ru(III)/Ru(II) couples of the bimetallic complex suggesting better metal–metal communication than classical polypyridyl analogues.
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