Zhantao Yang, Linlin Chen, Yuhang Zhao, Qianhui Chen, Wanjun Zhao, Linfei Li, Boxuan Zhang, Hua Xie, Xiangtao Kong and Chun-Hua Yang
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BCl3 catalyzed Z-selective intramolecular chlorocarbamoylation of alkynes/allenes†
A metal-free stereoselective intramolecular chlorocarbamoylation of alkynes/allenes driven by BCl3 was described, which provides a general and practical method for constructing versatile and chlorinated methylene lactams or tetrahydroisoquinolinones with (Z) geometry at the double bond, featuring a stereochemically defined tetrasubstituted chloroethene.
期刊介绍：
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.
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