{"title":"核苷酸粘合的可降解和可封闭循环使用的水下粘合剂","authors":"Mingsong Huang, Lingyu Liu, Wei Guo, Liying Cui, Guanghui Gao, Qin Zhang, Xin Liu","doi":"10.1002/adfm.202413542","DOIUrl":null,"url":null,"abstract":"Sustainable underwater adhesives have drawn much interest in promising applications and environmental engineering. However, developing a convenient strategy to combine recyclability and underwater adhesion into adhesive materials remains a formidable challenge. In this work, a degradable and closed-loop recyclable underwater adhesive tackifier is designed by nucleotide, via the ring-opening polymerization of thioctic acid in the presence of 5′-adenosine monophosphate and methacrylatoethyl trimethyl ammonium chloride. The nucleotide-tackified adhesives present an excellent underwater adhesion for various materials, tissues, and on-demand detachment adhesion behavior. The underwater adhesives demonstrate reusability, degradability, and closed-loop recyclability of dual monomers of thioctic acid and 5′-adenosine monophosphate. Interestingly, the waste residues of the underwater adhesives demonstrate processability and can be employed again in the construction of tough adhesive interfaces in both air and underwater, with further expanding sustainability. It is envisioned that the strategy of nucleotide-tackified sustainable underwater adhesives would offer promising insights for advancing sustainable and recyclable adhesive materials.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":null,"pages":null},"PeriodicalIF":18.5000,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Nucleotide-Tackified Degradable and Closed-Loop Recyclable Underwater Adhesive\",\"authors\":\"Mingsong Huang, Lingyu Liu, Wei Guo, Liying Cui, Guanghui Gao, Qin Zhang, Xin Liu\",\"doi\":\"10.1002/adfm.202413542\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Sustainable underwater adhesives have drawn much interest in promising applications and environmental engineering. However, developing a convenient strategy to combine recyclability and underwater adhesion into adhesive materials remains a formidable challenge. In this work, a degradable and closed-loop recyclable underwater adhesive tackifier is designed by nucleotide, via the ring-opening polymerization of thioctic acid in the presence of 5′-adenosine monophosphate and methacrylatoethyl trimethyl ammonium chloride. The nucleotide-tackified adhesives present an excellent underwater adhesion for various materials, tissues, and on-demand detachment adhesion behavior. The underwater adhesives demonstrate reusability, degradability, and closed-loop recyclability of dual monomers of thioctic acid and 5′-adenosine monophosphate. Interestingly, the waste residues of the underwater adhesives demonstrate processability and can be employed again in the construction of tough adhesive interfaces in both air and underwater, with further expanding sustainability. It is envisioned that the strategy of nucleotide-tackified sustainable underwater adhesives would offer promising insights for advancing sustainable and recyclable adhesive materials.\",\"PeriodicalId\":112,\"journal\":{\"name\":\"Advanced Functional Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":18.5000,\"publicationDate\":\"2024-09-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Functional Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/adfm.202413542\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202413542","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Nucleotide-Tackified Degradable and Closed-Loop Recyclable Underwater Adhesive
Sustainable underwater adhesives have drawn much interest in promising applications and environmental engineering. However, developing a convenient strategy to combine recyclability and underwater adhesion into adhesive materials remains a formidable challenge. In this work, a degradable and closed-loop recyclable underwater adhesive tackifier is designed by nucleotide, via the ring-opening polymerization of thioctic acid in the presence of 5′-adenosine monophosphate and methacrylatoethyl trimethyl ammonium chloride. The nucleotide-tackified adhesives present an excellent underwater adhesion for various materials, tissues, and on-demand detachment adhesion behavior. The underwater adhesives demonstrate reusability, degradability, and closed-loop recyclability of dual monomers of thioctic acid and 5′-adenosine monophosphate. Interestingly, the waste residues of the underwater adhesives demonstrate processability and can be employed again in the construction of tough adhesive interfaces in both air and underwater, with further expanding sustainability. It is envisioned that the strategy of nucleotide-tackified sustainable underwater adhesives would offer promising insights for advancing sustainable and recyclable adhesive materials.
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
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