Synthesis, Surface Chemistry, and Applications of Non‐Zero‐Dimensional Diamond Nanostructures

Diamond nanomaterials are renowned for their exceptional properties, which include the inherent attributes of bulk diamond. Additionally, they exhibit unique characteristics at the nanoscale, including high specific surface areas, tunable surface structure, and excellent biocompatibility. These multifaceted attributes have piqued the interest of researchers globally, leading to an extensive exploration of various diamond nanostructures in a myriad of applications. This review focuses on non‐zero‐dimensional (non‐0D) diamond nanostructures including diamond films and extended diamond nanostructures, such as diamond nanowires, nanoplatelets, and diamond foams. It delves into the fabrication, modification, and diverse applications of non‐0D diamond nanostructures. This review begins with a concise review of the preparation methods for different types of diamond films and extended nanostructures, followed by an exploration of the intricacies of surface termination and the process of immobilizing target moieties of interest. It then transitions into an exploration of the applications of diamond films and extended nanostructures in the fields of biomedicine and electrochemistry. In the concluding section, this article provides a forward‐looking perspective on the current state and future directions of diamond films and extended nanostructures research, offering insights into the opportunities and challenges that lie ahead in this exciting field.