作为可回收光子生物塑料的光子上转换晶体掺杂细菌纤维素复合薄膜

IF 7.5 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Communications Materials Pub Date : 2024-09-28 DOI:10.1038/s43246-024-00638-6
Pankaj Bharmoria, Lukas Naimovičius, Deyaa Abol-Fotouh, Mila Miroshnichenko, Justas Lekavičius, Gabriele De Luca, Umair Saeed, Karolis Kazlauskas, Nicolas Candau, Paulius Baronas, Anna Roig, Kasper Moth-Poulsen
{"title":"作为可回收光子生物塑料的光子上转换晶体掺杂细菌纤维素复合薄膜","authors":"Pankaj Bharmoria, Lukas Naimovičius, Deyaa Abol-Fotouh, Mila Miroshnichenko, Justas Lekavičius, Gabriele De Luca, Umair Saeed, Karolis Kazlauskas, Nicolas Candau, Paulius Baronas, Anna Roig, Kasper Moth-Poulsen","doi":"10.1038/s43246-024-00638-6","DOIUrl":null,"url":null,"abstract":"Biopolymers currently utilized as substitutes for synthetic polymers in photonics applications are predominantly confined to linear optical color responses. Herein we expand their applications in non-linear optics by integrating with triplet-triplet annihilation photon upconversion crystals. A photon upconverting biomaterial is prepared by cultivating Pd(II) meso-tetraphenyl tetrabenzoporphine: 9,10-diphenyl anthracene (sensitizer: annihilator) crystals on bacterial cellulose hydrogel that serves both as host and template for the crystallization of photon upconversion chromophores. Coating with gelatin improves the material’s optical transparency by adjusting the refractive indices. The prepared material shows an upconversion of 633 nm red light to 443 nm blue light, indicated by quadratic to linear dependence on excitation power density (non-linearly). Notably, components of this material are physically dis-assembled to retrieve 66 ± 1% of annihilator, at the end of life. Whereas, the residual clean biomass is subjected to biodegradation, showcasing the sustainability of the developed photonics material. Biopolymers used in photonics are mainly limited to linear optical color responses. Here, photon upconversion crystals incorporated into bacterial cellulose films demonstrate non-linear optical applications in biopolymers.","PeriodicalId":10589,"journal":{"name":"Communications Materials","volume":null,"pages":null},"PeriodicalIF":7.5000,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.com/articles/s43246-024-00638-6.pdf","citationCount":"0","resultStr":"{\"title\":\"Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics\",\"authors\":\"Pankaj Bharmoria, Lukas Naimovičius, Deyaa Abol-Fotouh, Mila Miroshnichenko, Justas Lekavičius, Gabriele De Luca, Umair Saeed, Karolis Kazlauskas, Nicolas Candau, Paulius Baronas, Anna Roig, Kasper Moth-Poulsen\",\"doi\":\"10.1038/s43246-024-00638-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Biopolymers currently utilized as substitutes for synthetic polymers in photonics applications are predominantly confined to linear optical color responses. Herein we expand their applications in non-linear optics by integrating with triplet-triplet annihilation photon upconversion crystals. A photon upconverting biomaterial is prepared by cultivating Pd(II) meso-tetraphenyl tetrabenzoporphine: 9,10-diphenyl anthracene (sensitizer: annihilator) crystals on bacterial cellulose hydrogel that serves both as host and template for the crystallization of photon upconversion chromophores. Coating with gelatin improves the material’s optical transparency by adjusting the refractive indices. The prepared material shows an upconversion of 633 nm red light to 443 nm blue light, indicated by quadratic to linear dependence on excitation power density (non-linearly). Notably, components of this material are physically dis-assembled to retrieve 66 ± 1% of annihilator, at the end of life. Whereas, the residual clean biomass is subjected to biodegradation, showcasing the sustainability of the developed photonics material. Biopolymers used in photonics are mainly limited to linear optical color responses. Here, photon upconversion crystals incorporated into bacterial cellulose films demonstrate non-linear optical applications in biopolymers.\",\"PeriodicalId\":10589,\"journal\":{\"name\":\"Communications Materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":7.5000,\"publicationDate\":\"2024-09-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.nature.com/articles/s43246-024-00638-6.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.nature.com/articles/s43246-024-00638-6\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.nature.com/articles/s43246-024-00638-6","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

目前,光子学应用中用作合成聚合物替代品的生物聚合物主要局限于线性光学色彩反应。在这里,我们通过与三重-三重湮灭光子上转换晶体的整合,拓展了它们在非线性光学领域的应用。一种光子上转换生物材料是通过培养钯(II)介四苯基四苯甲吗啡制备的:9,10-二苯基蒽(增感剂:湮灭剂)晶体,该晶体既是光子上转换发色团结晶的宿主,又是其模板。明胶涂层通过调整折射率提高了材料的光学透明度。所制备的材料可将 633 纳米红光上转换为 443 纳米蓝光,这与激发功率密度(非线性)呈二次到线性关系。值得注意的是,这种材料的组件在使用寿命结束时会被物理分解,以回收 66±1% 的湮灭剂。而残留的清洁生物质则会发生生物降解,从而体现出所开发光子材料的可持续性。光子学中使用的生物聚合物主要局限于线性光学颜色响应。在这里,融入细菌纤维素薄膜的光子上转换晶体展示了生物聚合物中的非线性光学应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Photon upconversion crystals doped bacterial cellulose composite films as recyclable photonic bioplastics
Biopolymers currently utilized as substitutes for synthetic polymers in photonics applications are predominantly confined to linear optical color responses. Herein we expand their applications in non-linear optics by integrating with triplet-triplet annihilation photon upconversion crystals. A photon upconverting biomaterial is prepared by cultivating Pd(II) meso-tetraphenyl tetrabenzoporphine: 9,10-diphenyl anthracene (sensitizer: annihilator) crystals on bacterial cellulose hydrogel that serves both as host and template for the crystallization of photon upconversion chromophores. Coating with gelatin improves the material’s optical transparency by adjusting the refractive indices. The prepared material shows an upconversion of 633 nm red light to 443 nm blue light, indicated by quadratic to linear dependence on excitation power density (non-linearly). Notably, components of this material are physically dis-assembled to retrieve 66 ± 1% of annihilator, at the end of life. Whereas, the residual clean biomass is subjected to biodegradation, showcasing the sustainability of the developed photonics material. Biopolymers used in photonics are mainly limited to linear optical color responses. Here, photon upconversion crystals incorporated into bacterial cellulose films demonstrate non-linear optical applications in biopolymers.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Communications Materials
Communications Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
12.10
自引率
1.30%
发文量
85
审稿时长
17 weeks
期刊介绍: Communications Materials, a selective open access journal within Nature Portfolio, is dedicated to publishing top-tier research, reviews, and commentary across all facets of materials science. The journal showcases significant advancements in specialized research areas, encompassing both fundamental and applied studies. Serving as an open access option for materials sciences, Communications Materials applies less stringent criteria for impact and significance compared to Nature-branded journals, including Nature Communications.
期刊最新文献
Thermodynamic evidence for polaron stabilization inside the antiferromagnetic order of Eu5In2Sb6 Benefits and complexity of defects in metal-organic frameworks Multi-sensing yarns for continuous wireless sweat lactate monitoring Unexpected band structure changes within the higher-temperature antiferromagnetic state of CeBi Bioengineering approach for the design of magnetic bacterial cellulose membranes
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1