集成亲和传播算法和空间双变量分析的框架,用于加强土壤重金属污染源的识别和定位。

IF 3.2 3区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Environmental Geochemistry and Health Pub Date : 2024-09-25 DOI:10.1007/s10653-024-02246-2
Feng Zhang, Shenglu Zhou, Zhenyi Jia, Xuefeng Xie, Mingxing Xu, Shaohua Wu
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引用次数: 0

摘要

准确识别污染源及其空间分布对于减轻土壤重金属(SHMs)污染至关重要。然而,受体模型难以有效地对污染源进行分类,并确定其位置和扩散趋势。我们提出了一个新颖的综合框架,将受体模型、随机森林(RF)、亲和传播(AP)算法和空间关联双变量局部指标(BLISA)结合起来,以优化传统的工业区 SHMs 源头追踪方法。我们利用受体模型结合射频法对 SHMs 来源进行了划分,同时采用 BLISA 结合 AP 法对来源区域进行了精确定位,并确定了其扩散趋势。结果表明,SHMs 来源于装备制造业集聚区和农业活动(59.0%)、地质背景(30.5%)以及重污染行业排放(10.5%)等混合污染源。土壤镉和铅的污染源位于特定工业附近,呈现出受工业场地影响的多场地并发污染扩散特征。铬、铜和锌污染源的空间分布集中在高密度的城市工业区,由点源向非点源过渡,其扩散模式受到工业空间聚集效应的影响。我们的增强框架能准确识别 SHMs 来源的位置及其扩散趋势,从而改善区域土壤污染管理。
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A framework integrating affinity propagation algorithm and spatial bivariate analysis for enhanced identification and localisation of soil heavy metals pollution sources.

The accurate identification of pollutant sources and their spatial distribution is crucial for mitigating soil heavy metals (SHMs) pollution. However, the receptor model struggles to effectively categorize pollutant sources and pinpoint their locations and dispersion trends. We propose a novel comprehensive framework that combines a receptor model, random forest (RF), affinity propagation (AP) algorithm, and bivariate local indicator of spatial association (BLISA), to optimize the traditional approach for tracing SHMs sources in industrial regions. We apportioned SHMs sources using a receptor model combined with RF, while BLISA combined with AP methods were employed to accurately locate the source areas and identify their dispersion tendencies. The results revealed that SHMs originated from mixed sources of equipment manufacturing agglomeration and agricultural activities (59.0%), geological background (30.5%), and emissions from heavily-polluting industries (10.5%). The pollution sources of soil Cd and Pb were located near specific industries, showing characteristics of multi-site concurrent pollution diffusion influenced by their proximity to industrial sites. The spatial distribution of Cr, Cu, and Zn sources was concentrated in high-density urban industrial areas, transitioning from point to nonpoint sources, with diffusion patterns influenced by the spatial agglomeration effect of industries. Our enhanced framework accurately identifies the location of SHMs sources and their dispersion tendencies, thereby improving regional soil pollution management.

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来源期刊
Environmental Geochemistry and Health
Environmental Geochemistry and Health 环境科学-工程:环境
CiteScore
8.00
自引率
4.80%
发文量
279
审稿时长
4.2 months
期刊介绍: Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people. Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes. The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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