{"title":"通过 Cu2+ 诱导传感器检测硫氰酸根离子的灵敏且具有选择性的光学化学传感器及其实际应用。","authors":"Parul Bhalla, Rajesh Malhotra","doi":"10.1007/s10895-024-03943-y","DOIUrl":null,"url":null,"abstract":"<p><p>In various fields, including analytical, environmental, and biochemistry, the detection of ions is significant. A simple probe, 3-(1-((4-aminophenyl)imino)ethyl)-4-hydroxy-6-methyl-2H-pyran-2-one (DPD), was designed for this study and used for the detection of Cu<sup>2+</sup> ions in methanol, based on dehydroacetic acid and phenylenediamine moieties. Binding interactions studies were performed using UV-Vis measurements, which showed selective binding behaviour towards Cu<sup>2+</sup> ions. The HRMS spectral data and Job's plot were used to check the stoichiometry ratio of 2:1 of a probe to Cu<sup>2+</sup> ions. A detection limit of 1.38×10<sup>-7</sup> M for Cu<sup>2+</sup> ions was observed. Theoretical DFT calculations were used to determine the quantum parameters and the energy gap between frontier molecular orbitals. Interestingly, the DPD-Cu<sup>2+</sup> complex acted as a probe for the detection of SCN<sup>-</sup> ions at a low LOD value, i.e., 1.97×10<sup>-7</sup> M. A novel incidence of reversibility with SCN<sup>-</sup> ions was reported using the HRMS technique. Next, real water and blood samples were used, and the concentration of Cu<sup>2+</sup> ions was calculated to further analyse the practical applicability of the probe. The DPD probe showed better selectivity and sensitivity than previously reported sensors, especially in complex matrices, where other sensors frequently experience interference and detection limit issues, indicating its potential as an advanced tool for ion detection in various applications.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Optical Chemosensor as a Sensitive and Selective Tool for the Detection of Thiocyanate Ions Via Cu<sup>2+</sup> Induced Sensor and Its Practical Application.\",\"authors\":\"Parul Bhalla, Rajesh Malhotra\",\"doi\":\"10.1007/s10895-024-03943-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>In various fields, including analytical, environmental, and biochemistry, the detection of ions is significant. A simple probe, 3-(1-((4-aminophenyl)imino)ethyl)-4-hydroxy-6-methyl-2H-pyran-2-one (DPD), was designed for this study and used for the detection of Cu<sup>2+</sup> ions in methanol, based on dehydroacetic acid and phenylenediamine moieties. Binding interactions studies were performed using UV-Vis measurements, which showed selective binding behaviour towards Cu<sup>2+</sup> ions. The HRMS spectral data and Job's plot were used to check the stoichiometry ratio of 2:1 of a probe to Cu<sup>2+</sup> ions. A detection limit of 1.38×10<sup>-7</sup> M for Cu<sup>2+</sup> ions was observed. Theoretical DFT calculations were used to determine the quantum parameters and the energy gap between frontier molecular orbitals. Interestingly, the DPD-Cu<sup>2+</sup> complex acted as a probe for the detection of SCN<sup>-</sup> ions at a low LOD value, i.e., 1.97×10<sup>-7</sup> M. A novel incidence of reversibility with SCN<sup>-</sup> ions was reported using the HRMS technique. Next, real water and blood samples were used, and the concentration of Cu<sup>2+</sup> ions was calculated to further analyse the practical applicability of the probe. The DPD probe showed better selectivity and sensitivity than previously reported sensors, especially in complex matrices, where other sensors frequently experience interference and detection limit issues, indicating its potential as an advanced tool for ion detection in various applications.</p>\",\"PeriodicalId\":15800,\"journal\":{\"name\":\"Journal of Fluorescence\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Fluorescence\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10895-024-03943-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fluorescence","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10895-024-03943-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
Optical Chemosensor as a Sensitive and Selective Tool for the Detection of Thiocyanate Ions Via Cu2+ Induced Sensor and Its Practical Application.
In various fields, including analytical, environmental, and biochemistry, the detection of ions is significant. A simple probe, 3-(1-((4-aminophenyl)imino)ethyl)-4-hydroxy-6-methyl-2H-pyran-2-one (DPD), was designed for this study and used for the detection of Cu2+ ions in methanol, based on dehydroacetic acid and phenylenediamine moieties. Binding interactions studies were performed using UV-Vis measurements, which showed selective binding behaviour towards Cu2+ ions. The HRMS spectral data and Job's plot were used to check the stoichiometry ratio of 2:1 of a probe to Cu2+ ions. A detection limit of 1.38×10-7 M for Cu2+ ions was observed. Theoretical DFT calculations were used to determine the quantum parameters and the energy gap between frontier molecular orbitals. Interestingly, the DPD-Cu2+ complex acted as a probe for the detection of SCN- ions at a low LOD value, i.e., 1.97×10-7 M. A novel incidence of reversibility with SCN- ions was reported using the HRMS technique. Next, real water and blood samples were used, and the concentration of Cu2+ ions was calculated to further analyse the practical applicability of the probe. The DPD probe showed better selectivity and sensitivity than previously reported sensors, especially in complex matrices, where other sensors frequently experience interference and detection limit issues, indicating its potential as an advanced tool for ion detection in various applications.
期刊介绍:
Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.