Tuning the structure and properties of carbon cloth by FeCl3intercalation for efficient two-electron oxygen reduction catalysis.

The advancement of various energy conversion and storage technologies hinges on the development of efficient and stable electrocatalysts for the oxygen reduction reaction (ORR). In this study, we report the enhancement of carbon cloth (CC) for robust ORR through an FeCl₃intercalation reaction. Utilizing a thermal annealing method, FeCl₃was intercalated into the graphite structure on the surface of CC, resulting in the creation of numerous defects and the incorporation of Fe species. These newly introduced defects play a pivotal role in activating the ORR via a two-electron pathway. The presence of Fe species further stabilizes the catalytic activity, leading to efficient and stable ORR performance. Our findings highlight the significance of defect engineering and Fe species incorporation in carbon-based materials for improved ORR catalysis and pave the way for the development of advanced electrocatalysts for energy-related applications.