用于增材制造的 AlSi12 粉末的爆炸特性和抑制分析

IF 3.6 3区 工程技术 Q2 ENGINEERING, CHEMICAL Journal of Loss Prevention in The Process Industries Pub Date : 2024-09-19 DOI:10.1016/j.jlp.2024.105439
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引用次数: 0

摘要

为防止 AlSi12 粉末在增材制造过程中发生爆炸事故,使用 20 L 球形爆炸装置研究了 AlSi12 的爆炸特性和 NaHCO₃ 的抑制效果。此外,还对爆炸残留物进行了热分析、化学成分和表面形态分析,以阐明抑制机制。结果表明,AlSi12 粉末的爆炸危害在浓度为 750 g/m³ 时达到最大,爆炸压力为 0.710 MPa,爆炸温度为 801 ℃。添加惰性比为 2.6 的 NaHCO3 能有效抑制所有浓度 AlSi12 粉末的爆炸。NaHCO3 对较高浓度的 AlSi12 有更好的抑制作用,与爆炸压力相比,对爆炸温度的抑制作用更大。此外,加入 NaHCO3 能有效抑制 AlSi12 灰尘云的氧化,提高 AlSi12 的表观活化能,从而降低爆炸概率。综合实验分析表明,NaHCO3 可通过吸热、阻止热传递、自由基捕获和反应物消耗等机制有效抑制 AlSi12 粉末爆炸。消耗的反应物主要是合金粉末中的铝元素,而硅元素基本不受影响。这些发现为预防和控制 AlSi12 粉末爆炸提供了宝贵的实验数据和理论支持。
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Explosion characteristics and suppression analysis of AlSi12 powder used in additive manufacturing
To prevent explosion accidents of AlSi12 powder during additive manufacturing, a 20- L spherical explosion apparatus was used to investigate the explosion characteristics of AlSi12 and the suppression effects of NaHCO₃. Additionally, thermal analysis, chemical composition, and surface morphology analysis of the explosion residues were conducted to clarify the suppression mechanisms. The results indicated that the explosion hazard of AlSi12 powder reached its maximum at a concentration of 750 g/m³, with an explosion pressure of 0.710 MPa and an explosion temperature of 801 °C. The addition of NaHCO3 at an inerting ratio of 2.6 effectively suppressed explosions across all concentrations of AlSi12 powder. NaHCO3 showed better inhibitory effects on higher concentrations of AlSi12, with greater suppression of explosion temperature compared to explosion pressure. Furthermore, incorporating NaHCO3 effectively inhibited the oxidation of AlSi12 dust clouds, increasing the apparent activation energy of AlSi12, thereby reducing the probability of explosion. Combined experimental analyses revealed that NaHCO3 effectively inhibits AlSi12 powder explosions through mechanisms such as heat absorption, prevention of heat transfer, radical capture, and reactant consumption. The consumed reactants are primarily the Al element in the alloy powder, while the Si element is largely unaffected. These findings provide valuable experimental data and theoretical support for preventing and controlling AlSi12 powder explosions.
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来源期刊
CiteScore
7.20
自引率
14.30%
发文量
226
审稿时长
52 days
期刊介绍: The broad scope of the journal is process safety. Process safety is defined as the prevention and mitigation of process-related injuries and damage arising from process incidents involving fire, explosion and toxic release. Such undesired events occur in the process industries during the use, storage, manufacture, handling, and transportation of highly hazardous chemicals.
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