{"title":"用于双面染料敏化太阳能电池的含银纳米线的复合电催化聚(3,4-亚乙二氧基噻吩)薄膜","authors":"","doi":"10.1016/j.electacta.2024.145132","DOIUrl":null,"url":null,"abstract":"<div><div>Poly(3,4-ethylenedioxythiophene) (PEDOT) is a superior electrocatalyst for dye-sensitized solar cells (DSSCs). The porous PEDOT film, however, lacks directional conduction paths, resulting in slower electron transfer and lower cell efficiency. In this study, silver nanowires (Ag NWs) are incorporated into a PEDOT film to construct a PEDOT-coated Ag NW composite film, wherein the Ag NWs serve as highways for charge transport. The composite film is constructed by spreading Ag NWs on tin-doped indium oxide (ITO) glass via a three-step process (dip coating, brush painting, and thermal compression), followed by coating a PEDOT film via electropolymerization. The DSSC catalyzed by the PEDOT-coated Ag NW exhibited an efficiency of 9.22 % under one-sun illumination, outperforming platinum (9.09 % efficiency) and PEDOT (8.33 % efficiency) by increasing the short-circuit current density. Chemical state analyses were performed to determine the interactions between the Ag NWs and PEDOT. Impedance measurements and quantum chemical calculations were conducted to rationalize the functionality of the PEDOT-coated Ag NWs. Owing to its high transparency, the resulting DSSC achieves an efficiency of 6.74 % under rear illumination, demonstrating its high feasibility as a bifacial DSSC. The DSSC also exhibited high efficiencies ranging from 14.05 % to 19.69 % under front-side illumination at low intensities of 300–1000 lux.</div></div>","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":null,"pages":null},"PeriodicalIF":5.5000,"publicationDate":"2024-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A composite electrocatalytic poly(3,4-ethylenedioxythiophene) film incorporated with silver nanowires for bifacial dye-sensitized solar cells\",\"authors\":\"\",\"doi\":\"10.1016/j.electacta.2024.145132\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Poly(3,4-ethylenedioxythiophene) (PEDOT) is a superior electrocatalyst for dye-sensitized solar cells (DSSCs). The porous PEDOT film, however, lacks directional conduction paths, resulting in slower electron transfer and lower cell efficiency. In this study, silver nanowires (Ag NWs) are incorporated into a PEDOT film to construct a PEDOT-coated Ag NW composite film, wherein the Ag NWs serve as highways for charge transport. The composite film is constructed by spreading Ag NWs on tin-doped indium oxide (ITO) glass via a three-step process (dip coating, brush painting, and thermal compression), followed by coating a PEDOT film via electropolymerization. The DSSC catalyzed by the PEDOT-coated Ag NW exhibited an efficiency of 9.22 % under one-sun illumination, outperforming platinum (9.09 % efficiency) and PEDOT (8.33 % efficiency) by increasing the short-circuit current density. Chemical state analyses were performed to determine the interactions between the Ag NWs and PEDOT. Impedance measurements and quantum chemical calculations were conducted to rationalize the functionality of the PEDOT-coated Ag NWs. Owing to its high transparency, the resulting DSSC achieves an efficiency of 6.74 % under rear illumination, demonstrating its high feasibility as a bifacial DSSC. The DSSC also exhibited high efficiencies ranging from 14.05 % to 19.69 % under front-side illumination at low intensities of 300–1000 lux.</div></div>\",\"PeriodicalId\":305,\"journal\":{\"name\":\"Electrochimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2024-09-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Electrochimica Acta\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0013468624013690\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochimica Acta","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0013468624013690","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
摘要
聚(3,4-亚乙二氧基噻吩)(PEDOT)是染料敏化太阳能电池(DSSC)的优质电催化剂。然而,多孔 PEDOT 薄膜缺乏定向传导路径,导致电子传输速度较慢,电池效率较低。在本研究中,银纳米线(Ag NWs)被加入到 PEDOT 薄膜中,从而构建出一种 PEDOT 涂层 Ag NW 复合薄膜,其中的 Ag NWs 可作为电荷传输的高速公路。这种复合薄膜是通过三步法(浸涂、刷涂和热压)在掺锡氧化铟(ITO)玻璃上铺展银纳米粒子,然后通过电聚合涂覆 PEDOT 薄膜而制成的。通过提高短路电流密度,由 PEDOT 涂层 Ag NW 催化的 DSSC 在一太阳光照下的效率达到了 9.22%,优于铂(效率 9.09%)和 PEDOT(效率 8.33%)。为确定 Ag NWs 和 PEDOT 之间的相互作用,进行了化学状态分析。此外,还进行了阻抗测量和量子化学计算,以合理解释 PEDOT 涂层 Ag NWs 的功能。由于其透明度高,所产生的 DSSC 在背光照明下的效率达到了 6.74%,证明了其作为双面 DSSC 的高度可行性。在 300-1000 勒克斯的低强度正面照明下,该 DSSC 还表现出 14.05% 至 19.69% 的高效率。
A composite electrocatalytic poly(3,4-ethylenedioxythiophene) film incorporated with silver nanowires for bifacial dye-sensitized solar cells
Poly(3,4-ethylenedioxythiophene) (PEDOT) is a superior electrocatalyst for dye-sensitized solar cells (DSSCs). The porous PEDOT film, however, lacks directional conduction paths, resulting in slower electron transfer and lower cell efficiency. In this study, silver nanowires (Ag NWs) are incorporated into a PEDOT film to construct a PEDOT-coated Ag NW composite film, wherein the Ag NWs serve as highways for charge transport. The composite film is constructed by spreading Ag NWs on tin-doped indium oxide (ITO) glass via a three-step process (dip coating, brush painting, and thermal compression), followed by coating a PEDOT film via electropolymerization. The DSSC catalyzed by the PEDOT-coated Ag NW exhibited an efficiency of 9.22 % under one-sun illumination, outperforming platinum (9.09 % efficiency) and PEDOT (8.33 % efficiency) by increasing the short-circuit current density. Chemical state analyses were performed to determine the interactions between the Ag NWs and PEDOT. Impedance measurements and quantum chemical calculations were conducted to rationalize the functionality of the PEDOT-coated Ag NWs. Owing to its high transparency, the resulting DSSC achieves an efficiency of 6.74 % under rear illumination, demonstrating its high feasibility as a bifacial DSSC. The DSSC also exhibited high efficiencies ranging from 14.05 % to 19.69 % under front-side illumination at low intensities of 300–1000 lux.
期刊介绍:
Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.