在基于 CEM 的电解槽中以二氧化碳为媒介将碳酸氢盐转化为浓甲酸盐

IF 13.1 1区 化学 Q1 Energy Journal of Energy Chemistry Pub Date : 2024-09-17 DOI:10.1016/j.jechem.2024.09.014
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引用次数: 0

摘要

可再生能源驱动的碳酸氢盐转化为有价值的化学物质为减少二氧化碳排放提供了一种极具吸引力的策略,因为碳酸氢盐可以通过使用具有反应吸收功能的碱性溶液捕获大气中的二氧化碳而高效生成。在这项工作中,我们使用阳离子交换膜电解槽(电极面积为 25 cm2),将二氧化碳介导的碳酸氢盐转化为纯甲酸盐。在总电流为 2.5 A 的情况下,我们的电解法对甲酸盐的选择性超过 75%,甲酸盐浓度高达 1.2 M,长期产量高达 95%。技术经济评估证实了该工艺的经济可行性,突出了碳酸氢盐电解作为生产有价值化学品的可持续方法的潜力。
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CO2-mediated bicarbonate conversion to concentrated formate in a CEM-based electrolyzer
Renewable energy-driven bicarbonate conversion to valuable chemicals presents an attractive strategy for mitigating CO2 emissions, as bicarbonate can be efficiently generated from the capture of atmospheric CO2 using alkaline solutions with reactive absorption. In this work, we present a CO2-mediated bicarbonate conversion to pure formate using a cation exchange membrane-based electrolyzer with a 25 cm2 electrode area. Our electrolysis achieved selectivities exceeding 75% for formate at a total current of 2.5 A, achieving formate concentrations up to 1.2 M and yields as high as 95% over extended periods. The techno-economic assessment confirmed the economic viability of the process, highlighting the potential for bicarbonate electrolysis as a sustainable method for producing valuable chemicals.
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来源期刊
Journal of Energy Chemistry
Journal of Energy Chemistry CHEMISTRY, APPLIED-CHEMISTRY, PHYSICAL
CiteScore
19.10
自引率
8.40%
发文量
3631
审稿时长
15 days
期刊介绍: The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies. This journal focuses on original research papers covering various topics within energy chemistry worldwide, including: Optimized utilization of fossil energy Hydrogen energy Conversion and storage of electrochemical energy Capture, storage, and chemical conversion of carbon dioxide Materials and nanotechnologies for energy conversion and storage Chemistry in biomass conversion Chemistry in the utilization of solar energy
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