{"title":"作为钠离子电池高效阳极材料的单层钛酸钠纳米颗粒","authors":"Qingbing Xia, Yaru Liang, Emily R. Cooper, Cheng-Lin Ko, Zhe Hu, Weijie Li, Shulei Chou, Ruth Knibbe","doi":"10.1002/aenm.202400929","DOIUrl":null,"url":null,"abstract":"Monolayer atomic crystals show significant advantages in improving charge storage kinetics for electrode materials. While notable progress is made, challenges remain in producing nanocrystals with desirable configurations, dimensions, and crystallographic properties. Here, 1D single-crystal nanobelts assembled from monolayer sodium titanate nanobelts are reported with highly exposed active sites as anode materials for sodium-ion batteries (SIBs). The unique structural properties of the 1D single-crystal nanobelts offer excellent electrochemical activity, electrochemo-mechanical stability, and well-maintained structural integrity, leading to highly efficient sodium ion storage performance. Insights into the electrochemical reaction processes, as revealed by in situ transmission electron microscopy, in situ synchrotron X-ray diffraction, and theoretical calculations, indicate that the 1D single-crystal nanobelts enable favorable sodium ion storage kinetics and a low-strain characteristic. This facilitates fast charge/discharge capability and long-term cycling stability for up to 5000 cycles at 20 C. Moreover, the 1D single-crystal nanobelts demonstrate practical applicability. A pouch cell assembled with the 1D single-crystal nanobelts anode and iron-based Prussian blue cathode exhibits highly stable cycling, achieving a low capacity fading ratio of ≈0.05% per cycle over 150 cycles. 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引用次数: 0
摘要
单层原子晶体在改善电极材料的电荷储存动力学方面具有显著优势。虽然取得了显著进展,但在生产具有理想构型、尺寸和晶体学特性的纳米晶体方面仍存在挑战。本文报告了由单层钛酸钠纳米颗粒组装而成的一维单晶纳米颗粒,其活性位点高度暴露,可作为钠离子电池(SIB)的负极材料。一维单晶纳米颗粒的独特结构特性提供了优异的电化学活性、电化学机械稳定性和良好的结构完整性,从而实现了高效的钠离子存储性能。原位透射电子显微镜、原位同步辐射 X 射线衍射和理论计算对电化学反应过程的深入研究表明,一维单晶纳米颗粒具有良好的钠离子存储动力学和低应变特性。此外,一维单晶纳米颗粒还证明了其实用性。由一维单晶纳米颗粒阳极和铁基普鲁士蓝阴极组装而成的袋式电池具有高度稳定的循环性能,在 150 个循环周期内,每个循环的容量衰减率低至≈0.05%。这项研究为通过智能结构纳米工程增强电极材料的电荷存储能力提供了一种创新的设计原理。
Monolayer Sodium Titanate Nanobelts as a Highly Efficient Anode Material for Sodium-Ion Batteries
Monolayer atomic crystals show significant advantages in improving charge storage kinetics for electrode materials. While notable progress is made, challenges remain in producing nanocrystals with desirable configurations, dimensions, and crystallographic properties. Here, 1D single-crystal nanobelts assembled from monolayer sodium titanate nanobelts are reported with highly exposed active sites as anode materials for sodium-ion batteries (SIBs). The unique structural properties of the 1D single-crystal nanobelts offer excellent electrochemical activity, electrochemo-mechanical stability, and well-maintained structural integrity, leading to highly efficient sodium ion storage performance. Insights into the electrochemical reaction processes, as revealed by in situ transmission electron microscopy, in situ synchrotron X-ray diffraction, and theoretical calculations, indicate that the 1D single-crystal nanobelts enable favorable sodium ion storage kinetics and a low-strain characteristic. This facilitates fast charge/discharge capability and long-term cycling stability for up to 5000 cycles at 20 C. Moreover, the 1D single-crystal nanobelts demonstrate practical applicability. A pouch cell assembled with the 1D single-crystal nanobelts anode and iron-based Prussian blue cathode exhibits highly stable cycling, achieving a low capacity fading ratio of ≈0.05% per cycle over 150 cycles. This study provides an innovative design principle to enhance the charge storage capability of electrode materials through intelligent structural nanoengineering.
期刊介绍:
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.