从糖到脂肪胺:听起来那么甜?生物基脂肪胺的生产和应用。

IF 40.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chemical Society Reviews Pub Date : 2024-10-04 DOI:10.1039/d4cs00244j
Benjamin Vermeeren, Sofie Van Praet, Wouter Arts, Thomas Narmon, Yingtuan Zhang, Cheng Zhou, Hans P Steenackers, Bert F Sels
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引用次数: 0

摘要

脂肪族胺是一类种类繁多的胺,包括烷基胺、烷基多胺、烷醇胺和脂肪族杂环胺。其结构多样性和独特性使其成为从化学和技术到农业和医药等多个工业领域中不可或缺的成分。目前,脂肪族胺的工业生产正面临着紧迫的可持续发展、健康和安全问题,这些问题都是由于对化石原料的严重依赖而产生的。有趣的是,这些问题可以通过转向使用生物质作为原料得到根本解决。在这方面,纤维素和半纤维素(木质纤维素的碳水化合物部分)是生产脂肪胺的理想原料,因为它们数量丰富、使用安全,而且其脂肪族骨架容易发生化学变化。因此,过去几年来,学术界对通过(半)纤维素衍生底物的催化还原胺化反应生产生物基脂肪胺的兴趣有了系统性的提高。然而,从工业角度来看,生物基脂肪胺的生产只是一个更大的、理想的循环价值链的中间环节。这条价值链的第一部分还包括将生物质原料提炼成合适的基质,最后一部分是将这些脂肪胺应用于各种领域。本综述将介绍生物基脂肪族胺价值链的每个部分。从整体角度出发,我们可以认识到每个部分的要求和局限性,并有效地发现和弥补不同部分之间的知识差距。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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From sugars to aliphatic amines: as sweet as it sounds? Production and applications of bio-based aliphatic amines.

Aliphatic amines encompass a diverse group of amines that include alkylamines, alkyl polyamines, alkanolamines and aliphatic heterocyclic amines. Their structural diversity and distinctive characteristics position them as indispensable components across multiple industrial domains, ranging from chemistry and technology to agriculture and medicine. Currently, the industrial production of aliphatic amines is facing pressing sustainability, health and safety issues which all arise due to the strong dependency on fossil feedstock. Interestingly, these issues can be fundamentally resolved by shifting toward biomass as the feedstock. In this regard, cellulose and hemicellulose, the carbohydrate fraction of lignocellulose, emerge as promising feedstock for the production of aliphatic amines as they are available in abundance, safe to use and their aliphatic backbone is susceptible to chemical transformations. Consequently, the academic interest in bio-based aliphatic amines via the catalytic reductive amination of (hemi)cellulose-derived substrates has systematically increased over the past years. From an industrial perspective, however, the production of bio-based aliphatic amines will only be the middle part of a larger, ideally circular, value chain. This value chain additionally includes, as the first part, the refinery of the biomass feedstock to suitable substrates and, as the final part, the implementation of these aliphatic amines in various applications. Each part of the bio-based aliphatic amine value chain will be covered in this Review. Applying a holistic perspective enables one to acknowledge the requirements and limitations of each part and to efficiently spot and potentially bridge knowledge gaps between the different parts.

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来源期刊
Chemical Society Reviews
Chemical Society Reviews 化学-化学综合
CiteScore
80.80
自引率
1.10%
发文量
345
审稿时长
6.0 months
期刊介绍: Chemical Society Reviews is published by: Royal Society of Chemistry. Focus: Review articles on topics of current interest in chemistry; Predecessors: Quarterly Reviews, Chemical Society (1947–1971); Current title: Since 1971; Impact factor: 60.615 (2021); Themed issues: Occasional themed issues on new and emerging areas of research in the chemical sciences
期刊最新文献
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