利用梯形笼高度选择性地识别氟化物。

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-10-04 DOI:10.1039/D4OB01465K

Ruiye Wu, Caihong Mao, Feiying Ruan, Yan Cai and Xiaobo Hu

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引用次数: 0

摘要

通过使用梯形笼 (1)，在由大量过量的各种常见阴离子组成的高度竞争环境中实现了对 F- 的高选择性识别（S > 1000）。通过核磁共振、荧光、紫外可见光和 HRMS 研究，展示了 1 + F- 的结合行为和结合亲和力（β2 = ∼107 M-2）。

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Highly selective recognition of fluoride using a trapezoidal cage†

By using a trapezoidal cage (1), highly selective recognition of F⁻ (S > 1000) was achieved in highly competitive environments composed of a large excess of various common anions. Through NMR, fluorescence, UV-vis and HRMS studies, the binding behavior and binding affinity (β₂ = ∼10⁷ M⁻²) of 1 + F⁻ are shown.

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来源期刊

ACS Applied Bio Materials Chemistry-Chemistry (all)

CiteScore

9.40

自引率

2.10%

发文量

464