{"title":"揭开高级氧化过程中氧化反应物的神秘面纱:房间里的大象","authors":"Jing-Hang Wu, Han-Qing Yu","doi":"10.1021/acs.est.4c06725","DOIUrl":null,"url":null,"abstract":"Advanced oxidation processes (AOPs) are rapidly evolving but still lack well-established protocols for reliably identifying oxidative reactive species (ORSs). This Perspective presents both the radical and nonradical ORSs that have been identified or proposed, along with the extensive controversies surrounding oxidative mechanisms. Conventional identification tools, such as quenchers, probes, and spin trappers, might be inadequate for the analytical demands of systems in which multiple ORSs coexist, often yielding misleading results. Therefore, the challenges of identifying these complex, short-lived, and transient ORSs must be fully acknowledged. Refining analytical methods for ORSs is necessary, supported by rigorous experiments and innovative paradigms, particularly through kinetic analysis based on <i>in situ</i> spectroscopic techniques and multiple-probe strategies. To demystify these complex ORSs, future efforts should be made to develop advanced tools and strategies to enhance the mechanism understanding. In addition, integrating real-world conditions into experimental designs will establish a reliable framework in fundamental studies, providing more accurate insights and effectively guiding the design of AOPs.","PeriodicalId":36,"journal":{"name":"环境科学与技术","volume":null,"pages":null},"PeriodicalIF":10.8000,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Confronting the Mysteries of Oxidative Reactive Species in Advanced Oxidation Processes: An Elephant in the Room\",\"authors\":\"Jing-Hang Wu, Han-Qing Yu\",\"doi\":\"10.1021/acs.est.4c06725\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Advanced oxidation processes (AOPs) are rapidly evolving but still lack well-established protocols for reliably identifying oxidative reactive species (ORSs). This Perspective presents both the radical and nonradical ORSs that have been identified or proposed, along with the extensive controversies surrounding oxidative mechanisms. Conventional identification tools, such as quenchers, probes, and spin trappers, might be inadequate for the analytical demands of systems in which multiple ORSs coexist, often yielding misleading results. Therefore, the challenges of identifying these complex, short-lived, and transient ORSs must be fully acknowledged. Refining analytical methods for ORSs is necessary, supported by rigorous experiments and innovative paradigms, particularly through kinetic analysis based on <i>in situ</i> spectroscopic techniques and multiple-probe strategies. To demystify these complex ORSs, future efforts should be made to develop advanced tools and strategies to enhance the mechanism understanding. In addition, integrating real-world conditions into experimental designs will establish a reliable framework in fundamental studies, providing more accurate insights and effectively guiding the design of AOPs.\",\"PeriodicalId\":36,\"journal\":{\"name\":\"环境科学与技术\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":10.8000,\"publicationDate\":\"2024-10-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"环境科学与技术\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.est.4c06725\",\"RegionNum\":1,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"环境科学与技术","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.est.4c06725","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Confronting the Mysteries of Oxidative Reactive Species in Advanced Oxidation Processes: An Elephant in the Room
Advanced oxidation processes (AOPs) are rapidly evolving but still lack well-established protocols for reliably identifying oxidative reactive species (ORSs). This Perspective presents both the radical and nonradical ORSs that have been identified or proposed, along with the extensive controversies surrounding oxidative mechanisms. Conventional identification tools, such as quenchers, probes, and spin trappers, might be inadequate for the analytical demands of systems in which multiple ORSs coexist, often yielding misleading results. Therefore, the challenges of identifying these complex, short-lived, and transient ORSs must be fully acknowledged. Refining analytical methods for ORSs is necessary, supported by rigorous experiments and innovative paradigms, particularly through kinetic analysis based on in situ spectroscopic techniques and multiple-probe strategies. To demystify these complex ORSs, future efforts should be made to develop advanced tools and strategies to enhance the mechanism understanding. In addition, integrating real-world conditions into experimental designs will establish a reliable framework in fundamental studies, providing more accurate insights and effectively guiding the design of AOPs.
期刊介绍:
Environmental Science & Technology (ES&T) is a co-sponsored academic and technical magazine by the Hubei Provincial Environmental Protection Bureau and the Hubei Provincial Academy of Environmental Sciences.
Environmental Science & Technology (ES&T) holds the status of Chinese core journals, scientific papers source journals of China, Chinese Science Citation Database source journals, and Chinese Academic Journal Comprehensive Evaluation Database source journals. This publication focuses on the academic field of environmental protection, featuring articles related to environmental protection and technical advancements.