用于二锌催化开环聚合的苯胺桥接双（吡唑）烷配体

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-10-11 DOI:10.1039/D4DT02837F

Pratyush K. Naik, Zipeng Gu and Robert J. Comito

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引用次数: 0

摘要

我们报告了一种具有两个双（吡唑）烷臂的苯胺配体（1）及其阳离子二锌配合物。通过 XRD、NMR 和对二锌配合物的建模，我们发现了一种前所未有的动态  苯胺核心。与已发表的 -苯酚类似物相比，我们的 -anilide 复合物在 rac-lactide 的开环聚合反应中显示出更高的活性和不同的反离子趋势。

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An aniline-bridged bis(pyrazolyl)alkane ligand for dizinc-catalysed ring-opening polymerization†

We report an aniline ligand (1) with two bis(pyrazolyl)alkane arms, and its cationic, dizinc complexes. XRD, NMR, and modelling of the dizinc complexes resulted in an unprecedented, dynamic μ-anilide core. Compared with published μ-phenolate analogues, our μ-anilide complexes show higher activity and divergent counterion trends in ring-opening polymerization of rac-lactide.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.