具有良好光传感性能的凯夫拉尔和对聚苯二胺共轭复合材料的制备与表征

IF 0.9 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Russian Journal of General Chemistry Pub Date : 2024-10-04 DOI:10.1134/S1070363224080292
E. G. Zaki, H. M. Abd El-Salam, M. Rabia
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引用次数: 0

摘要

成功合成了一种新型导电共轭复合材料,包括 Kevlar 和对聚苯二胺(Kevlar/PPPD)纳米复合材料。这些技术对 Kevlar 复合材料的结构和光学特性提供了宝贵的见解,肯定了其在聚合物光电探测器中的应用潜力。随后,对 Kevlar/PPPD 纳米复合材料进行了严格的测试,以评估其作为光电探测器的性能。在这些实验中,在两种不同的条件下测量了纳米复合材料产生的电流密度(Jph):无光(暗)和有光。结果显示,电流明显增加,从黑暗条件下的 0.32 mA 增加到光照条件下的 0.58 mA。此外,研究还评估了两个关键参数,即光致共振(R)和特定检测率(D)。R 值持续下降,从最初的 2.7 毫安/瓦过渡到较低的 1.65 毫安/瓦。同样,比检测度 (D) 值从 6.2×107 琼斯下降到 3.8×107 琼斯,分别对应波长为 340 纳米和 540 纳米。这项研究的与众不同之处在于 Kevlar/PPPD 复合材料能够对包括紫外线(UV)、可见光(Vis)和近红外(IR)区域在内的一系列波长做出有效响应。这种宽光谱响应能力使 Kevlar 复合材料成为各种光电检测应用中极具潜力的候选材料。因此,Kevlar/PPPD 复合材料展示了其作为光电探测器在各种应用中的多功能性和潜在适用性。
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Preparation and Characterization of Conjugated Composite of Kevlar and p-Polyphenylenediamine with a Great Light Sensing Behavior

A novel conductive and conjugated composite, comprising Kevlar and p-polyphenylenediamine (Kevlar/PPPD) nanocomposite, was successfully synthesized. These techniques provided valuable insights into the structural and optical properties of the Kevlar composite, affirming its potential for applications in polymer photodetectors. Subsequently, the Kevlar/PPPD nanocomposite underwent rigorous testing to evaluate its performance as a photodetector. During these experiments, the current density generated by the nanocomposite (Jph) was measured under two distinct conditions: in the absence of light (dark) and in the presence of light. The results revealed a notable increase in current, rising from 0.32 mA in the dark to 0.58 mA under illuminated conditions. Additionally, the study assessed two crucial parameters, namely photoresponsivity (R) and specific detectivity (D). The R values displayed a consistent decrease, transitioning from an initial value of 2.7 mA/W to a lower value of 1.65 mA/W. Similarly, the specific detectivity (D) values declined from 6.2×107 to 3.8×107 Jones, corresponding to wavelengths of 340 and 540 nm, respectively. What sets this research apart is the Kevlar/PPPD composite’s ability to respond effectively to a range of wavelengths, encompassing ultraviolet (UV), visible (Vis), and near-infrared (IR) regions. This broad-spectrum responsiveness positions the Kevlar composite as a highly promising candidate for various photodetection applications. Consequently, the Kevlar/PPPD composite demonstrates its versatility and potential suitability for deployment as a photodetector in a diverse array of applications.

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来源期刊
CiteScore
1.40
自引率
22.20%
发文量
252
审稿时长
2-4 weeks
期刊介绍: Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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