{"title":"KBаLu(MoO4)3:Er3+/Yb3+ 上转换荧光粉的合成与表征","authors":"N. M. Kozhevnikova","doi":"10.1134/S0020168523100059","DOIUrl":null,"url":null,"abstract":"<p>A ternary molybdate with the composition KBаLu(MoO<sub>4</sub>)<sub>3</sub> and a monoclinic scheelite-like structure has been synthesized. Codoping KBаLu(MoO<sub>4</sub>)<sub>3</sub> with Er<sup>3+</sup>/Yb<sup>3+</sup> ions, we have obtained an upconversion phosphor exhibiting anti-Stokes luminescence in the range 400–700 nm under IR excitation. The synthesized phosphor has been characterized by X-ray diffraction, differential thermal analysis, and vibrational spectroscopy, and its IR, Raman, and luminescence spectra have been measured.</p>","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"59 10","pages":"1097 - 1103"},"PeriodicalIF":0.9000,"publicationDate":"2024-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of a KBаLu(MoO4)3:Er3+/Yb3+ Upconversion Phosphor\",\"authors\":\"N. M. Kozhevnikova\",\"doi\":\"10.1134/S0020168523100059\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A ternary molybdate with the composition KBаLu(MoO<sub>4</sub>)<sub>3</sub> and a monoclinic scheelite-like structure has been synthesized. Codoping KBаLu(MoO<sub>4</sub>)<sub>3</sub> with Er<sup>3+</sup>/Yb<sup>3+</sup> ions, we have obtained an upconversion phosphor exhibiting anti-Stokes luminescence in the range 400–700 nm under IR excitation. The synthesized phosphor has been characterized by X-ray diffraction, differential thermal analysis, and vibrational spectroscopy, and its IR, Raman, and luminescence spectra have been measured.</p>\",\"PeriodicalId\":585,\"journal\":{\"name\":\"Inorganic Materials\",\"volume\":\"59 10\",\"pages\":\"1097 - 1103\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-03-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0020168523100059\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S0020168523100059","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
我们合成了一种成分为 KBаLu(MoO4)3、结构类似单斜白钨矿的三元钼酸盐。通过将 KBаLu(MoO4)3与 Er3+/Yb3+ 离子偶联,我们获得了一种上转换荧光粉,在红外激发下,其发光波长范围为 400-700 纳米。我们利用 X 射线衍射、差热分析和振动光谱对合成的荧光粉进行了表征,并测量了其红外光谱、拉曼光谱和发光光谱。
Synthesis and Characterization of a KBаLu(MoO4)3:Er3+/Yb3+ Upconversion Phosphor
A ternary molybdate with the composition KBаLu(MoO4)3 and a monoclinic scheelite-like structure has been synthesized. Codoping KBаLu(MoO4)3 with Er3+/Yb3+ ions, we have obtained an upconversion phosphor exhibiting anti-Stokes luminescence in the range 400–700 nm under IR excitation. The synthesized phosphor has been characterized by X-ray diffraction, differential thermal analysis, and vibrational spectroscopy, and its IR, Raman, and luminescence spectra have been measured.
期刊介绍:
Inorganic Materials is a journal that publishes reviews and original articles devoted to chemistry, physics, and applications of various inorganic materials including high-purity substances and materials. The journal discusses phase equilibria, including P–T–X diagrams, and the fundamentals of inorganic materials science, which determines preparatory conditions for compounds of various compositions with specified deviations from stoichiometry. Inorganic Materials is a multidisciplinary journal covering all classes of inorganic materials. The journal welcomes manuscripts from all countries in the English or Russian language.