M. S. Avdontceva, A. A. Zolotarev, S. V. Krivovichev
{"title":"Rb3SO4F：晶体结构和热行为的改进","authors":"M. S. Avdontceva, A. A. Zolotarev, S. V. Krivovichev","doi":"10.1134/S108765962460025X","DOIUrl":null,"url":null,"abstract":"<p>The crystal structure and thermal behavior of Rb<sub>3</sub>SO<sub>4</sub>F a new compound is studied by in situ single-crystal X-ray diffraction analysis in a wide temperature range. The compound is stable up to a temperature of 377(10)°C and does not undergo phase transitions during heating. Calculation of the coefficients of the thermal expansion tensor showed that the structure expands strongly anisotropically: the maximum thermal expansion is observed in the <i>ab</i> plane, while the minimum is parallel to the [001] direction, which is closely correlated to changes in bond lengths and angles in the anion-centered FRb<sub>6</sub> octahedron.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"50 2","pages":"191 - 195"},"PeriodicalIF":0.8000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rb3SO4F: Refinement of the Crystal Structure and Thermal Behavior\",\"authors\":\"M. S. Avdontceva, A. A. Zolotarev, S. V. Krivovichev\",\"doi\":\"10.1134/S108765962460025X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The crystal structure and thermal behavior of Rb<sub>3</sub>SO<sub>4</sub>F a new compound is studied by in situ single-crystal X-ray diffraction analysis in a wide temperature range. The compound is stable up to a temperature of 377(10)°C and does not undergo phase transitions during heating. Calculation of the coefficients of the thermal expansion tensor showed that the structure expands strongly anisotropically: the maximum thermal expansion is observed in the <i>ab</i> plane, while the minimum is parallel to the [001] direction, which is closely correlated to changes in bond lengths and angles in the anion-centered FRb<sub>6</sub> octahedron.</p>\",\"PeriodicalId\":580,\"journal\":{\"name\":\"Glass Physics and Chemistry\",\"volume\":\"50 2\",\"pages\":\"191 - 195\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-09-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Glass Physics and Chemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S108765962460025X\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass Physics and Chemistry","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S108765962460025X","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Rb3SO4F: Refinement of the Crystal Structure and Thermal Behavior
The crystal structure and thermal behavior of Rb3SO4F a new compound is studied by in situ single-crystal X-ray diffraction analysis in a wide temperature range. The compound is stable up to a temperature of 377(10)°C and does not undergo phase transitions during heating. Calculation of the coefficients of the thermal expansion tensor showed that the structure expands strongly anisotropically: the maximum thermal expansion is observed in the ab plane, while the minimum is parallel to the [001] direction, which is closely correlated to changes in bond lengths and angles in the anion-centered FRb6 octahedron.
期刊介绍：
Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
