银和铜催化的异氰酸酯环加成反应

IF 4.4 2区化学 Q2 CHEMISTRY, APPLIED Advanced Synthesis & Catalysis Pub Date : 2024-10-12 DOI:10.1002/adsc.202400994

fatemeh doraghi, Parsa Baghershahi, Farzad Gilaninezhad, Negar Mehdi zadeh Darban, Navid Dastyafteh, Milad Noori, Mohammad Mahdavi

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引用次数: 0

摘要

由于具有酸性 α 碳和异氰酸基等多个反应位点，异氰酸酯可在金属催化体系下通过环化反应成功参与合成各种五元和六元 N-heterocycles 。考虑到这种合成物的独特性和多功能性，我们在本综述中重点介绍了过去十年中银和铜催化的异氰酸酯环化反应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Silver and Copper‐Catalyzed Cycloaddition Reactions of Isocyanide Esters

Owing to multiple reactive sites, such as an acidic α‐carbon and an isocyano group, isocyanide esters can successfully participate in the synthesis of various five‐ and six‐membered N‐heterocycles through the cycloaddition reactions under metal‐catalyzed systems. Considering the unique and versatile functionality of this synthon, in this review, we have highlighted silver and copper‐catalyzed cycloadditions of isocyanide esters over the last decade.

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来源期刊

Advanced Synthesis & Catalysis 化学-应用化学

CiteScore

9.40

自引率

7.40%

发文量

447

审稿时长

1.8 months

期刊介绍： Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry. The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.