{"title":"基于亲水性羟基侧链调制的氟化聚(对三亚苯基靛蓝)阴离子交换膜,用于燃料电池","authors":"","doi":"10.1016/j.jechem.2024.09.008","DOIUrl":null,"url":null,"abstract":"<div><div>The development of alkaline fuel cells is moving forward at an accelerated pace, and the application of ether-free bonded polymers to anion exchange membranes (AEMs) has been widely investigated. However, the question of the “trade-off” between AEM ionic conductivity and dimensional stability remains difficult. The strategy of inducing microphase separation to improve the performance of AEM has attracted much attention recently, but the design of optimal molecular structures is still being explored. Here, this work introduced different ratios of 3-bromo-1,1,1-trifluoroacetone (<em>x</em> = 40, 50, and 60) into the main chain of poly(p-terphenylene isatin). Because fluorinated groups have excellent hydrophobicity, hydrophilic hydroxyl-containing side chains are introduced to jointly adjust the formation of phase separation structure. The results show that PTI-PTF<sub>50</sub>-NOH AEM with the appropriate fluorinated group ratio has the best ionic conductivity and alkali stability under the combined effect of both. It has an ionic conductivity of 133.83 mS cm<sup>−1</sup> at 80 °C. In addition, the OH<sup>−</sup> conductivity remains at 89% of the initial value at 80 °C and 3 M KOH for 1056 h of immersion. The cell polarization curve based on PTI-PTF<sub>50</sub>-NOH shows a power density of 734.76 mW cm<sup>−2</sup> at a current density of 1807.7 mA cm<sup>−2</sup>.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":null,"pages":null},"PeriodicalIF":13.1000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fluorinated poly(p-triphenylene isatin) anion exchange membranes based on hydrophilic hydroxyl side chain modulation for fuel cells\",\"authors\":\"\",\"doi\":\"10.1016/j.jechem.2024.09.008\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The development of alkaline fuel cells is moving forward at an accelerated pace, and the application of ether-free bonded polymers to anion exchange membranes (AEMs) has been widely investigated. However, the question of the “trade-off” between AEM ionic conductivity and dimensional stability remains difficult. The strategy of inducing microphase separation to improve the performance of AEM has attracted much attention recently, but the design of optimal molecular structures is still being explored. Here, this work introduced different ratios of 3-bromo-1,1,1-trifluoroacetone (<em>x</em> = 40, 50, and 60) into the main chain of poly(p-terphenylene isatin). Because fluorinated groups have excellent hydrophobicity, hydrophilic hydroxyl-containing side chains are introduced to jointly adjust the formation of phase separation structure. The results show that PTI-PTF<sub>50</sub>-NOH AEM with the appropriate fluorinated group ratio has the best ionic conductivity and alkali stability under the combined effect of both. It has an ionic conductivity of 133.83 mS cm<sup>−1</sup> at 80 °C. In addition, the OH<sup>−</sup> conductivity remains at 89% of the initial value at 80 °C and 3 M KOH for 1056 h of immersion. The cell polarization curve based on PTI-PTF<sub>50</sub>-NOH shows a power density of 734.76 mW cm<sup>−2</sup> at a current density of 1807.7 mA cm<sup>−2</sup>.</div></div>\",\"PeriodicalId\":15728,\"journal\":{\"name\":\"Journal of Energy Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":13.1000,\"publicationDate\":\"2024-09-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Energy Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2095495624006296\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Energy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2095495624006296","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Energy","Score":null,"Total":0}
引用次数: 0
摘要
碱性燃料电池的开发正在加速进行,无醚键合聚合物在阴离子交换膜(AEM)中的应用已得到广泛研究。然而,如何在 AEM 离子导电性和尺寸稳定性之间进行 "权衡 "仍然是一个难题。最近,诱导微相分离以提高 AEM 性能的策略引起了广泛关注,但最佳分子结构的设计仍在探索之中。在此,本研究将不同比例的 3-溴-1,1,1-三氟丙酮(x = 40、50 和 60)引入聚对苯二甲酸丁二酯的主链中。由于氟化基团具有优异的疏水性,因此引入了亲水性的含羟基侧链,以共同调节相分离结构的形成。结果表明,在两者的共同作用下,具有适当氟化基比例的 PTI-PTF50-NOH AEM 具有最佳的离子导电性和碱稳定性。它在 80 °C 时的离子电导率为 133.83 mS cm-1。此外,在 80 °C 和 3 M KOH 溶液中浸泡 1056 小时后,羟基电导率仍保持在初始值的 89%。基于 PTI-PTF50-NOH 的电池极化曲线显示,在电流密度为 1807.7 mA cm-2 时,功率密度为 734.76 mW cm-2。
Fluorinated poly(p-triphenylene isatin) anion exchange membranes based on hydrophilic hydroxyl side chain modulation for fuel cells
The development of alkaline fuel cells is moving forward at an accelerated pace, and the application of ether-free bonded polymers to anion exchange membranes (AEMs) has been widely investigated. However, the question of the “trade-off” between AEM ionic conductivity and dimensional stability remains difficult. The strategy of inducing microphase separation to improve the performance of AEM has attracted much attention recently, but the design of optimal molecular structures is still being explored. Here, this work introduced different ratios of 3-bromo-1,1,1-trifluoroacetone (x = 40, 50, and 60) into the main chain of poly(p-terphenylene isatin). Because fluorinated groups have excellent hydrophobicity, hydrophilic hydroxyl-containing side chains are introduced to jointly adjust the formation of phase separation structure. The results show that PTI-PTF50-NOH AEM with the appropriate fluorinated group ratio has the best ionic conductivity and alkali stability under the combined effect of both. It has an ionic conductivity of 133.83 mS cm−1 at 80 °C. In addition, the OH− conductivity remains at 89% of the initial value at 80 °C and 3 M KOH for 1056 h of immersion. The cell polarization curve based on PTI-PTF50-NOH shows a power density of 734.76 mW cm−2 at a current density of 1807.7 mA cm−2.
期刊介绍:
The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies.
This journal focuses on original research papers covering various topics within energy chemistry worldwide, including:
Optimized utilization of fossil energy
Hydrogen energy
Conversion and storage of electrochemical energy
Capture, storage, and chemical conversion of carbon dioxide
Materials and nanotechnologies for energy conversion and storage
Chemistry in biomass conversion
Chemistry in the utilization of solar energy