{"title":"利用基于碳量子点的荧光传感器快速测定果汁中的有机磷杀虫剂残留量","authors":"","doi":"10.1016/j.jfca.2024.106816","DOIUrl":null,"url":null,"abstract":"<div><div>Nitrogen doped carbon quantum dots (N-CQDs) were synthesized by a hydrothermal method. A fluorescence sensor for rapid determination of organophosphorus pesticides residue was developed using the N-CQDs based on acetylcholine enzyme inhibition. Cu<sup>2+</sup> effectively quenched the strong fluorescence of N-CQDs, which could be recovered due to the complexation between copper ions and thiocholine, the hydrolysis product of acetylthiocholine catalyzed by acetylcholinesterase. Organophosphorus pesticides inhibited the activity of acetylcholinesterase, resulting in fluorescence quenching of N-CQDs. Fluorescence inhibiting efficiency depends on the concentration of the analytes, and therefore, the sensor could be used for quantitative analysis of organophosphorus pesticides residue. The average recoveries of the analytes ranged from 85.33 % to 110.67 % at the spiked concentrations of 0.015 mg/L, 0.04 mg/L and 0.1 mg/L, and the limits of detection were 2.89 ∼6.40 ng/mL. The developed method had the advantages of simple operation, fast speed, low cost, expensive apparatus-free, and environmental friendliness, which could be used for rapid screening of organophosphorus pesticides residue in real samples.</div></div>","PeriodicalId":15867,"journal":{"name":"Journal of Food Composition and Analysis","volume":null,"pages":null},"PeriodicalIF":4.0000,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rapid determination of organophosphorus insecticides residue in fruit juice by a fluorescence sensor based on carbon quantum dots\",\"authors\":\"\",\"doi\":\"10.1016/j.jfca.2024.106816\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Nitrogen doped carbon quantum dots (N-CQDs) were synthesized by a hydrothermal method. A fluorescence sensor for rapid determination of organophosphorus pesticides residue was developed using the N-CQDs based on acetylcholine enzyme inhibition. Cu<sup>2+</sup> effectively quenched the strong fluorescence of N-CQDs, which could be recovered due to the complexation between copper ions and thiocholine, the hydrolysis product of acetylthiocholine catalyzed by acetylcholinesterase. Organophosphorus pesticides inhibited the activity of acetylcholinesterase, resulting in fluorescence quenching of N-CQDs. Fluorescence inhibiting efficiency depends on the concentration of the analytes, and therefore, the sensor could be used for quantitative analysis of organophosphorus pesticides residue. The average recoveries of the analytes ranged from 85.33 % to 110.67 % at the spiked concentrations of 0.015 mg/L, 0.04 mg/L and 0.1 mg/L, and the limits of detection were 2.89 ∼6.40 ng/mL. The developed method had the advantages of simple operation, fast speed, low cost, expensive apparatus-free, and environmental friendliness, which could be used for rapid screening of organophosphorus pesticides residue in real samples.</div></div>\",\"PeriodicalId\":15867,\"journal\":{\"name\":\"Journal of Food Composition and Analysis\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2024-10-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Food Composition and Analysis\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0889157524008500\",\"RegionNum\":2,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Food Composition and Analysis","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0889157524008500","RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Rapid determination of organophosphorus insecticides residue in fruit juice by a fluorescence sensor based on carbon quantum dots
Nitrogen doped carbon quantum dots (N-CQDs) were synthesized by a hydrothermal method. A fluorescence sensor for rapid determination of organophosphorus pesticides residue was developed using the N-CQDs based on acetylcholine enzyme inhibition. Cu2+ effectively quenched the strong fluorescence of N-CQDs, which could be recovered due to the complexation between copper ions and thiocholine, the hydrolysis product of acetylthiocholine catalyzed by acetylcholinesterase. Organophosphorus pesticides inhibited the activity of acetylcholinesterase, resulting in fluorescence quenching of N-CQDs. Fluorescence inhibiting efficiency depends on the concentration of the analytes, and therefore, the sensor could be used for quantitative analysis of organophosphorus pesticides residue. The average recoveries of the analytes ranged from 85.33 % to 110.67 % at the spiked concentrations of 0.015 mg/L, 0.04 mg/L and 0.1 mg/L, and the limits of detection were 2.89 ∼6.40 ng/mL. The developed method had the advantages of simple operation, fast speed, low cost, expensive apparatus-free, and environmental friendliness, which could be used for rapid screening of organophosphorus pesticides residue in real samples.
期刊介绍:
The Journal of Food Composition and Analysis publishes manuscripts on scientific aspects of data on the chemical composition of human foods, with particular emphasis on actual data on composition of foods; analytical methods; studies on the manipulation, storage, distribution and use of food composition data; and studies on the statistics, use and distribution of such data and data systems. The Journal''s basis is nutrient composition, with increasing emphasis on bioactive non-nutrient and anti-nutrient components. Papers must provide sufficient description of the food samples, analytical methods, quality control procedures and statistical treatments of the data to permit the end users of the food composition data to evaluate the appropriateness of such data in their projects.
The Journal does not publish papers on: microbiological compounds; sensory quality; aromatics/volatiles in food and wine; essential oils; organoleptic characteristics of food; physical properties; or clinical papers and pharmacology-related papers.