通过控制基于 PVDF 的聚合物电容器的绝缘性能增强其储能特性

IF 5.4 2区 医学 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Biomaterials Science & Engineering Pub Date : 2024-10-08 DOI:10.1016/j.est.2024.114072
Zhiguo Wen , Chong Tian , Jing Ru , Xiang Wang
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引用次数: 0

摘要

在储能和电绝缘领域,本研究阐明了通过浇铸法合成的聚偏二氟乙烯(PVDF)和聚乙二醇(PEG800)混合薄膜的创新制造方法及其特性。这项研究的精髓在于将 PEG800 融合到聚偏二氟乙烯基体中,这一战略举措大大增强了所制复合材料的绝缘能力,在 50 MV/m 的电场条件下,泄漏电流从 2.61E-7 A 骤降至 3.50E-9A。值得注意的是,当 PEG800 的最佳质量分数为 30% 时,复合薄膜在 650 MV/m 的强大电场下可达到 34.6 J/cm3 的非凡储能密度。这项研究不仅展示了 70PVDF/30PEG800 薄膜卓越的能量存储和快速充放电特性,特别是在放电时间(t0.9)为 66 ns 的情况下,而且还强调了这种混合薄膜在革新聚合物薄膜电容器的设计和功能方面的潜力,标志着向可持续和高效的能量存储解决方案迈出了重要的一步。
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Enhancing energy storage properties via controlled insulation properties of PVDF-based polymer capacitors
In the realm of energy storage and electrical insulation, this study illuminates the innovative fabrication and consequent properties of polyvinylidene fluoride (PVDF) and polyethylene glycol (PEG800) blend films, synthesized via the casting method. The essence of this research lies in the integration of PEG800 into the PVDF matrix, a strategic move that significantly bolsters the insulation capabilities of the resulting composite, underscored by a dramatic decrease in leakage current from 2.61E-7 A to 3.50E-9 A at an electric field of 50 MV/m. Notably, at an optimal PEG800 mass fraction of 30 %, the composite film unveils an extraordinary energy storage density of 34.6 J/cm3 under the formidable electric field of 650 MV/m. This study not only shows cases the superior energy storage and rapid charge-discharge characteristics, particularly with a discharge time (t0.9) of 66 ns of the 70PVDF/30PEG800 film, but also underscores the potential of such blend films in revolutionizing the design and functionality of polymer film capacitors, marking a significant stride towards sustainable and efficient energy storage solutions.
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来源期刊
ACS Biomaterials Science & Engineering
ACS Biomaterials Science & Engineering Materials Science-Biomaterials
CiteScore
10.30
自引率
3.40%
发文量
413
期刊介绍: ACS Biomaterials Science & Engineering is the leading journal in the field of biomaterials, serving as an international forum for publishing cutting-edge research and innovative ideas on a broad range of topics: Applications and Health – implantable tissues and devices, prosthesis, health risks, toxicology Bio-interactions and Bio-compatibility – material-biology interactions, chemical/morphological/structural communication, mechanobiology, signaling and biological responses, immuno-engineering, calcification, coatings, corrosion and degradation of biomaterials and devices, biophysical regulation of cell functions Characterization, Synthesis, and Modification – new biomaterials, bioinspired and biomimetic approaches to biomaterials, exploiting structural hierarchy and architectural control, combinatorial strategies for biomaterials discovery, genetic biomaterials design, synthetic biology, new composite systems, bionics, polymer synthesis Controlled Release and Delivery Systems – biomaterial-based drug and gene delivery, bio-responsive delivery of regulatory molecules, pharmaceutical engineering Healthcare Advances – clinical translation, regulatory issues, patient safety, emerging trends Imaging and Diagnostics – imaging agents and probes, theranostics, biosensors, monitoring Manufacturing and Technology – 3D printing, inks, organ-on-a-chip, bioreactor/perfusion systems, microdevices, BioMEMS, optics and electronics interfaces with biomaterials, systems integration Modeling and Informatics Tools – scaling methods to guide biomaterial design, predictive algorithms for structure-function, biomechanics, integrating bioinformatics with biomaterials discovery, metabolomics in the context of biomaterials Tissue Engineering and Regenerative Medicine – basic and applied studies, cell therapies, scaffolds, vascularization, bioartificial organs, transplantation and functionality, cellular agriculture
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