壳聚糖/CNDs 涂层铜电极表面具有电能应用潜力

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引用次数: 0

摘要

聚合物和纳米材料已广泛应用于电化学化学传感器和生物传感器。技术能源的开发仍然十分必要,尤其是使用天然环保材料。生物聚合物壳聚糖和纳米材料碳纳米管(CNDs)因其非凡的性能而备受研究。研究重点是应用于电能的壳聚糖和壳聚糖/CNDs 纳米复合材料表面。采用电镀法在铜电极表面涂覆纳米复合材料。将涂层电极浸入油样中。然后通过傅立叶变换红外光谱、X 射线衍射、扫描电镜和化学传感器对浸渍后的纳米复合材料进行表征。傅立叶变换红外光谱和 X 射线衍射仪证实,纳米复合材料的结构仍然保持其化学成分,在 CNDs 互穿之后,壳聚糖的胺基、羟基和结晶度仍然保持不变。纳米复合材料的表面形貌显示,壳聚糖和 CNDs 纳米复合材料的电极表面都有磁铁矿颗粒分布,这一点已被扫描电镜证实。自由浸渍法以敏感材料壳聚糖/CNDs 作为化学传感器;壳聚糖/CNDs 敏感材料表面的加压过程会引起金属离子和酸性化合物的相互作用、这涉及一个离子渗透过程,在蒸发过程中被激发的油原子会因电子传输而发生原子振动,然后化学传感器上的活性基团直接吸收并结合油中的金属和酸,使用化学吸附过程,导致电荷从吸附颗粒转移到化学传感器表面,以填充孔洞,从而产生电势差,形成电脉冲,然后由 Arduino 系统捕获并转换成数字数据。这一过程使电能形式的技术能源生产变得更快。
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Chitosan/CNDs coated Cu electrode surface has an electrical potential for electrical energy application
Polymers and nanomaterials had been widely applied at electrochemical chemosensor and biosensor. Developing technical energy is still much needed, especially using natural environmental friendly material. Both chitosan of biopolymer and carbon nanodots (CNDs) of nanomaterials are highly studied due to their extraordinary properties. The research focus on chitosan and chitosan/CNDs nanocomposite surface that was applied for electrical energy. Nanocomposite was coated on Cu electrode surface by using electroplating method. The coated electrode was dipped into oil samples. The dipped nanocomposite then was characterized by FTIR, XRD, SEM, and Chemosensor. Nanocomposite structure is still maintain its chemical compound, confirmed by FTIR and XRD, which still maintain amine group; hydroxyl group; and crystalinity of chitosan after CNDs intercoporation. Nanocomposite surface morphology show magnetite particle distribution that spreaded on the surface of electrode for both chitosan and CNDs nanocomposite, which is confirmed by SEM. The free dipping method is based on the sensitive material chitosan/CNDs as a chemosensor; the pressure process on the surface of the chitosan/CNDs sensitive material causes the interaction of metal ions and acid compounds, which involves an iontophoresis process where oil atoms that have been excited in the evaporation process will experience atomic vibrations due to electron transport which then the active groups on the Chemosensor directly absorb and bind metals and acids in oil use a chemisorption process which leads to the transfer of charge from the adsorption particles to the chemosensor surface to fill the holes so that a potential difference occurs in the form of electrical pulses which will then be captured by the Arduino system which will be converted into digital data. This process makes technological energy production in the form of electrical energy faster.
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来源期刊
CiteScore
8.40
自引率
0.00%
发文量
100
审稿时长
33 weeks
期刊介绍: The journal has a particular interest in publishing papers on the unique issues facing chemical engineering taking place in countries that are rich in resources but face specific technical and societal challenges, which require detailed knowledge of local conditions to address. Core topic areas are: Environmental process engineering • treatment and handling of waste and pollutants • the abatement of pollution, environmental process control • cleaner technologies • waste minimization • environmental chemical engineering • water treatment Reaction Engineering • modelling and simulation of reactors • transport phenomena within reacting systems • fluidization technology • reactor design Separation technologies • classic separations • novel separations Process and materials synthesis • novel synthesis of materials or processes, including but not limited to nanotechnology, ceramics, etc. Metallurgical process engineering and coal technology • novel developments related to the minerals beneficiation industry • coal technology Chemical engineering education • guides to good practice • novel approaches to learning • education beyond university.
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