Yuanhao Wang , Lan Luo , Chunliang Yang , Quanlan Liao , Tianxiang Zhao
{"title":"利用废聚苯乙烯合成多孔超交联聚合物，实现高效二氧化碳分离","authors":"Yuanhao Wang , Lan Luo , Chunliang Yang , Quanlan Liao , Tianxiang Zhao","doi":"10.1016/j.micromeso.2024.113360","DOIUrl":null,"url":null,"abstract":"<div><div>A series of porous hypercrosslinked polymers (HCP-x) were synthesized from waste polystyrene foam via Fridel-Crafts alkylation reaction, aiming to optimize the utilization of waste plastics. The impact of various crosslinkers on the structural characteristics and CO<sub>2</sub> adsorption properties of HCP-x was investigated. The results indicated that HCP-x polymers possess high specific surface areas spanning 830–1182 m<sup>2</sup> g<sup>−1</sup>, abundant narrow micropores, and exceptional thermal stability. Notably, HCP-2 exhibited the highest CO<sub>2</sub> adsorption capacity of 2.77 mmol g<sup>−1</sup> at 273 K and 1.0 bar. These hypercrosslinked polymers also demonstrated a favorable CO<sub>2</sub>/N<sub>2</sub> ideal selectivity and robust cyclic adsorption performance. Breakthrough experiments confirmed the selective adsorption of CO2 from simulated flue gas containing CO<sub>2</sub>/N<sub>2</sub> (15/85). Additionally, the mechanism underlying CO<sub>2</sub> adsorption on HCP-x was elucidated by analyzing adsorption thermodynamics and diffusion kinetics. This study not only introduces an innovative method for recycling waste polystyrene foam but also underscores the potential of HCP-x as an effective adsorbent for CO<sub>2</sub> capture.</div></div>","PeriodicalId":392,"journal":{"name":"Microporous and Mesoporous Materials","volume":"381 ","pages":"Article 113360"},"PeriodicalIF":4.8000,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of porous hypercrosslinked polymers from waste polystyrene for efficient CO2 separation\",\"authors\":\"Yuanhao Wang , Lan Luo , Chunliang Yang , Quanlan Liao , Tianxiang Zhao\",\"doi\":\"10.1016/j.micromeso.2024.113360\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series of porous hypercrosslinked polymers (HCP-x) were synthesized from waste polystyrene foam via Fridel-Crafts alkylation reaction, aiming to optimize the utilization of waste plastics. The impact of various crosslinkers on the structural characteristics and CO<sub>2</sub> adsorption properties of HCP-x was investigated. The results indicated that HCP-x polymers possess high specific surface areas spanning 830–1182 m<sup>2</sup> g<sup>−1</sup>, abundant narrow micropores, and exceptional thermal stability. Notably, HCP-2 exhibited the highest CO<sub>2</sub> adsorption capacity of 2.77 mmol g<sup>−1</sup> at 273 K and 1.0 bar. These hypercrosslinked polymers also demonstrated a favorable CO<sub>2</sub>/N<sub>2</sub> ideal selectivity and robust cyclic adsorption performance. Breakthrough experiments confirmed the selective adsorption of CO2 from simulated flue gas containing CO<sub>2</sub>/N<sub>2</sub> (15/85). Additionally, the mechanism underlying CO<sub>2</sub> adsorption on HCP-x was elucidated by analyzing adsorption thermodynamics and diffusion kinetics. This study not only introduces an innovative method for recycling waste polystyrene foam but also underscores the potential of HCP-x as an effective adsorbent for CO<sub>2</sub> capture.</div></div>\",\"PeriodicalId\":392,\"journal\":{\"name\":\"Microporous and Mesoporous Materials\",\"volume\":\"381 \",\"pages\":\"Article 113360\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2024-10-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Microporous and Mesoporous Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1387181124003822\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous and Mesoporous Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1387181124003822","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Synthesis of porous hypercrosslinked polymers from waste polystyrene for efficient CO2 separation
A series of porous hypercrosslinked polymers (HCP-x) were synthesized from waste polystyrene foam via Fridel-Crafts alkylation reaction, aiming to optimize the utilization of waste plastics. The impact of various crosslinkers on the structural characteristics and CO2 adsorption properties of HCP-x was investigated. The results indicated that HCP-x polymers possess high specific surface areas spanning 830–1182 m2 g−1, abundant narrow micropores, and exceptional thermal stability. Notably, HCP-2 exhibited the highest CO2 adsorption capacity of 2.77 mmol g−1 at 273 K and 1.0 bar. These hypercrosslinked polymers also demonstrated a favorable CO2/N2 ideal selectivity and robust cyclic adsorption performance. Breakthrough experiments confirmed the selective adsorption of CO2 from simulated flue gas containing CO2/N2 (15/85). Additionally, the mechanism underlying CO2 adsorption on HCP-x was elucidated by analyzing adsorption thermodynamics and diffusion kinetics. This study not only introduces an innovative method for recycling waste polystyrene foam but also underscores the potential of HCP-x as an effective adsorbent for CO2 capture.
期刊介绍：
Microporous and Mesoporous Materials covers novel and significant aspects of porous solids classified as either microporous (pore size up to 2 nm) or mesoporous (pore size 2 to 50 nm). The porosity should have a specific impact on the material properties or application. Typical examples are zeolites and zeolite-like materials, pillared materials, clathrasils and clathrates, carbon molecular sieves, ordered mesoporous materials, organic/inorganic porous hybrid materials, or porous metal oxides. Both natural and synthetic porous materials are within the scope of the journal.
Topics which are particularly of interest include:
All aspects of natural microporous and mesoporous solids
The synthesis of crystalline or amorphous porous materials
The physico-chemical characterization of microporous and mesoporous solids, especially spectroscopic and microscopic
The modification of microporous and mesoporous solids, for example by ion exchange or solid-state reactions
All topics related to diffusion of mobile species in the pores of microporous and mesoporous materials
Adsorption (and other separation techniques) using microporous or mesoporous adsorbents
Catalysis by microporous and mesoporous materials
Host/guest interactions
Theoretical chemistry and modelling of host/guest interactions
All topics related to the application of microporous and mesoporous materials in industrial catalysis, separation technology, environmental protection, electrochemistry, membranes, sensors, optical devices, etc.
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