使用烷醇胺和亚硝酸钙混合物抑制氯化钠溶液中碳钢的腐蚀:电化学和显微镜评估

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY International Journal of Electrochemical Science Pub Date : 2024-09-18 DOI:10.1016/j.ijoes.2024.100802
Xiaohua Chen, Zhanshan Wang, Shuang Yu, Guixia Li
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引用次数: 0

摘要

使用由烷醇胺和硝酸钙组成的复合阻锈剂研究了碳钢在 3.50 % NaCl 腐蚀溶液中的阻锈性能。在 3.500 % NaCl 腐蚀溶液条件下,对钢材腐蚀进行了电化学阻抗谱和表面显微测试,得到了不同比例阻锈剂(烷醇胺、亚硝酸钙)对混凝土中钢材腐蚀的交流阻抗谱曲线和显微形貌。分析了复合阻锈剂对钢材锈蚀过程的影响。结果表明,由 0.50 % 的醇胺和 0.50 % 的亚硝酸钙组成的复合阻锈剂可延长钢筋锈蚀时间,降低锈蚀速率,在相同环境下,钢筋的锈蚀速率仅为 1.27 mm year-1,阻锈效率(η)为 97.8 %。对比各组的微观结构发现,使用复合阻锈剂的钢棒表面钝化膜致密,未发现锈斑,很好地保护了钢棒,达到了阻锈效果。
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Corrosion inhibition of carbon steel in NaCl solution Using a mixture of alkanol amine and calcium nitrite: Electrochemical and microscopic evaluation
The corrosion inhibition properties of carbon steel in 3.50 % NaCl corrosion solution were studied by using a compound rust inhibitor composed of alkanol amine and calcium nitrate. The electrochemical impedance spectrum and surface microscopic tests on steel corrosion were carried out under the condition of 3.500 % NaCl corrosion solution, and the AC impedance spectrum curve and microscopic morphology of different proportion of rust inhibitors (alkanol amines, calcium nitrite) on steel corrosion in concrete were obtained. The influence of composite rust inhibitors on steel corrosion process was analyzed. The results show that the composite rust inhibitor composed of 0.50 % alcoholamine and 0.50 % calcium nitrite can prolong the time of steel corrosion and decrease the corrosion rate, in the same environment, the corrosion rate of the steel bar is only 1.27 mm year−1, and the corrosion inhibition efficiency (η) is 97.8 %. Comparing the microstructure of each group, it was found that the passivation film on the surface of the steel bar with the composite rust inhibitor was dense, and no rust spots were found, which protected the steel bar well and achieved the effect of rust inhibition.
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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