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{"title":"基于共价有机框架的纳米复合材料的进展:用于减少和储存二氧化碳的先锋材料","authors":"Pallavi Singh, Pragnesh N Dave","doi":"10.1002/ghg.2297","DOIUrl":null,"url":null,"abstract":"<p>The persistent increase in atmospheric carbon dioxide (CO<sub>2</sub>) concentration poses a significant contemporary challenge. Contemporary chemistry is heavily focused on sustainable solutions, particularly the photo-/electrocatalytic reduction of CO<sub>2</sub> and its utilization for energy storage. Despite promising prospects, efficient chemical CO<sub>2</sub> conversion faces obstacles such as ineffective CO<sub>2</sub> uptake/activation and catalyst mass transport. Covalent organic frameworks (COFs) have emerged as potential catalysts due to their precise structural design, functionalizable chemical environments, and robust architectures. COF-based materials, especially those incorporating diverse active sites like single metal sites, metal nanoparticles, and metal oxides, hold promise for CO<sub>2</sub> conversion and energy storage. This review sheds light on CO<sub>2</sub> photoreduction/electroreduction and storage in Li-CO<sub>2</sub> batteries catalyzed by COF-based composites, focusing on recent advancements in integrating COFs with nanoparticles for CO<sub>2</sub> reduction. It discusses design principles, synthesis methods, and catalytic mechanisms driving the enhanced performance of COF-based nanocomposites across various applications, including electrochemical reduction, photocatalysis, and lithium CO<sub>2</sub> batteries. The review also addresses challenges and prospects of COF-based catalysts for efficient CO<sub>2</sub> utilization, aiming to steer the development of innovative COF-based nanocomposites, thus advancing sustainable energy technologies and environmental stewardship. © 2024 Society of Chemical Industry and John Wiley & Sons, Ltd.</p>","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Advancements in covalent organic framework-based nanocomposites: Pioneering materials for CO2 reduction and storage\",\"authors\":\"Pallavi Singh, Pragnesh N Dave\",\"doi\":\"10.1002/ghg.2297\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The persistent increase in atmospheric carbon dioxide (CO<sub>2</sub>) concentration poses a significant contemporary challenge. Contemporary chemistry is heavily focused on sustainable solutions, particularly the photo-/electrocatalytic reduction of CO<sub>2</sub> and its utilization for energy storage. Despite promising prospects, efficient chemical CO<sub>2</sub> conversion faces obstacles such as ineffective CO<sub>2</sub> uptake/activation and catalyst mass transport. Covalent organic frameworks (COFs) have emerged as potential catalysts due to their precise structural design, functionalizable chemical environments, and robust architectures. COF-based materials, especially those incorporating diverse active sites like single metal sites, metal nanoparticles, and metal oxides, hold promise for CO<sub>2</sub> conversion and energy storage. This review sheds light on CO<sub>2</sub> photoreduction/electroreduction and storage in Li-CO<sub>2</sub> batteries catalyzed by COF-based composites, focusing on recent advancements in integrating COFs with nanoparticles for CO<sub>2</sub> reduction. It discusses design principles, synthesis methods, and catalytic mechanisms driving the enhanced performance of COF-based nanocomposites across various applications, including electrochemical reduction, photocatalysis, and lithium CO<sub>2</sub> batteries. The review also addresses challenges and prospects of COF-based catalysts for efficient CO<sub>2</sub> utilization, aiming to steer the development of innovative COF-based nanocomposites, thus advancing sustainable energy technologies and environmental stewardship. © 2024 Society of Chemical Industry and John Wiley & Sons, Ltd.</p>\",\"PeriodicalId\":12796,\"journal\":{\"name\":\"Greenhouse Gases: Science and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Greenhouse Gases: Science and Technology\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ghg.2297\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Greenhouse Gases: Science and Technology","FirstCategoryId":"93","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ghg.2297","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
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