Shahzad Ameen , Aleena Tahir , Tanveer ul Haq , Ammar Ahmed Khan , Mira Tul Zubaida Butt , Irshad Hussain , Syed Zajif Hussain , Habib ur Rehman
{"title":"推动可持续能源：聚氧化金属（POM）在光电化学制氢中的作用","authors":"Shahzad Ameen , Aleena Tahir , Tanveer ul Haq , Ammar Ahmed Khan , Mira Tul Zubaida Butt , Irshad Hussain , Syed Zajif Hussain , Habib ur Rehman","doi":"10.1016/j.ccr.2024.216265","DOIUrl":null,"url":null,"abstract":"<div><div>This review elucidates the pivotal role of polyoxometalates (POMs) in photoelectrochemical (PEC) water splitting, an emerging field with profound implications for sustainable hydrogen production. POMs, characterized by their versatile metal oxide clusters, exhibit remarkable efficacy as co-catalysts, enhancing the efficiency and performance of PEC systems. Through precise modulation of charge separation dynamics and promotion of efficient charge transfer kinetics at the semiconductor-electrolyte interface, POMs significantly augment the overall efficiency of PEC devices. Their inherent attributes, including broad-spectrum light absorption and exceptional chemical stability, underscore their suitability for solar-driven electrolysis, offering a viable pathway towards sustainable hydrogen generation. This review underscores the strategic importance of POMs in optimizing the functionality of key semiconductors employed in PEC, such as BiVO<sub>4</sub>, CdS, Si, Fe<sub>2</sub>O<sub>3</sub>, and TiO<sub>2</sub>, thereby advancing the frontiers of renewable energy conversion technologies. Additionally, the exploration of innovative strategies for enhancing POM-based photoelectrodes, encompassing tailored surface modifications and synergistic tandem cell configurations, underscores the indispensable role of POMs in catalyzing the transition towards efficient and scalable hydrogen production methodologies.</div></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":"523 ","pages":"Article 216265"},"PeriodicalIF":20.3000,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Driving sustainable energy: The role of polyoxometalates (POMs) in photoelectrochemical hydrogen production\",\"authors\":\"Shahzad Ameen , Aleena Tahir , Tanveer ul Haq , Ammar Ahmed Khan , Mira Tul Zubaida Butt , Irshad Hussain , Syed Zajif Hussain , Habib ur Rehman\",\"doi\":\"10.1016/j.ccr.2024.216265\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>This review elucidates the pivotal role of polyoxometalates (POMs) in photoelectrochemical (PEC) water splitting, an emerging field with profound implications for sustainable hydrogen production. POMs, characterized by their versatile metal oxide clusters, exhibit remarkable efficacy as co-catalysts, enhancing the efficiency and performance of PEC systems. Through precise modulation of charge separation dynamics and promotion of efficient charge transfer kinetics at the semiconductor-electrolyte interface, POMs significantly augment the overall efficiency of PEC devices. Their inherent attributes, including broad-spectrum light absorption and exceptional chemical stability, underscore their suitability for solar-driven electrolysis, offering a viable pathway towards sustainable hydrogen generation. This review underscores the strategic importance of POMs in optimizing the functionality of key semiconductors employed in PEC, such as BiVO<sub>4</sub>, CdS, Si, Fe<sub>2</sub>O<sub>3</sub>, and TiO<sub>2</sub>, thereby advancing the frontiers of renewable energy conversion technologies. Additionally, the exploration of innovative strategies for enhancing POM-based photoelectrodes, encompassing tailored surface modifications and synergistic tandem cell configurations, underscores the indispensable role of POMs in catalyzing the transition towards efficient and scalable hydrogen production methodologies.</div></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":\"523 \",\"pages\":\"Article 216265\"},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2024-10-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854524006118\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524006118","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Driving sustainable energy: The role of polyoxometalates (POMs) in photoelectrochemical hydrogen production
This review elucidates the pivotal role of polyoxometalates (POMs) in photoelectrochemical (PEC) water splitting, an emerging field with profound implications for sustainable hydrogen production. POMs, characterized by their versatile metal oxide clusters, exhibit remarkable efficacy as co-catalysts, enhancing the efficiency and performance of PEC systems. Through precise modulation of charge separation dynamics and promotion of efficient charge transfer kinetics at the semiconductor-electrolyte interface, POMs significantly augment the overall efficiency of PEC devices. Their inherent attributes, including broad-spectrum light absorption and exceptional chemical stability, underscore their suitability for solar-driven electrolysis, offering a viable pathway towards sustainable hydrogen generation. This review underscores the strategic importance of POMs in optimizing the functionality of key semiconductors employed in PEC, such as BiVO4, CdS, Si, Fe2O3, and TiO2, thereby advancing the frontiers of renewable energy conversion technologies. Additionally, the exploration of innovative strategies for enhancing POM-based photoelectrodes, encompassing tailored surface modifications and synergistic tandem cell configurations, underscores the indispensable role of POMs in catalyzing the transition towards efficient and scalable hydrogen production methodologies.
期刊介绍：
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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