高功率激光熔覆 17-4PH 合金涂层的微观结构、机械性能和抗气蚀性能研究

IF 5.3 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2024-10-10 DOI:10.1016/j.surfcoat.2024.131451
Xu Liu, Li Meng, Xiaoyan Zeng, Beibei Zhu, Jiaming Cao, Kaiwen Wei, Qianwu Hu
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引用次数: 0

摘要

首次使用激光功率为 15 kW 的高功率激光熔覆(HPLC)工艺制造 17-4PH 合金涂层。HPLC 工艺的建模速率达到 272 mm3/s,明显超过了传统的低功率激光熔覆工艺(≤85 mm3/s)。随后,对不同老化温度(300-550 °C)下涂层的微观结构和机械性能进行了表征。此外,随着老化温度的升高,17-4PH 涂层的硬度、强度和塑性先上升后下降。在 480 ℃ 时,由于马氏体含量极高,且ε-Cu 沉淀的大小和数量达到最佳协同效应,断裂伸长率(19.5 ± 0.5 %)达到顶峰,是现有报告中的最高水平。硬度(436 ± 5 HV)和极限拉伸强度(1218 ± 8 MPa)也达到了低功率激光熔覆工艺的水平。最后,抗空化侵蚀(CER)测试结果表明,在去离子水中 480 °C 下老化的 17-4PH 涂层的 CER 是 0Cr13Ni5Mo 基体的 2.4 倍。17-4PH 涂层的高硬度和弹塑性是其 CER 值高于基体的关键因素。采用 HPLC 工艺制作的 17-4PH 涂层不仅具有更高的效率,而且还获得了显著的机械性能和 CER,可为水力发电设备(如 Pelton 转轮)的表面强化或修复提供一种前景广阔的解决方案。
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Study on the microstructure, mechanical properties and cavitation erosion resistance of 17-4PH alloy coatings fabricated by high power laser cladding
The high power laser cladding (HPLC) process with laser power of 15 kW was used for the first time to fabricate 17-4PH alloy coatings. The build rate of the HPLC process reached 272 mm3/s, markedly surpassing that of conventional low power laser cladding process (≤85 mm3/s). Subsequently, the microstructure and mechanical properties of the coatings at different aging temperatures (300–550 °C) was characterized. Moreover, with increasing aging temperature, the hardness, strength and plasticity of 17-4PH coting initially ascend before descending. At 480 °C, due to the remarkably high martensite content and the optimal synergy between the size and quantity of ε-Cu precipitates, the break elongation (19.5 ± 0.5 %) achieved its zenith, which is at the highest level in existing reports. The hardness (436 ± 5 HV) and ultimate tensile strength (1218 ± 8 MPa) have also reached the level of low power laser cladding process. Finally, the results of the cavitation erosion resistance (CER) testing indicate that the CER of the 17-4PH coating aged at 480 °C in deionized water is 2.4 times that of the 0Cr13Ni5Mo substrate. High hardness and elastic-plastic capability of the 17-4PH coating are the key factors for higher CER than the substrate. The 17-4PH coatings crafted by HPLC not only has higher efficiency, but also obtains remarkable mechanical performance and CER, which may provide a promising solution for surface strengthening or repair of hydroelectric power equipment such as Pelton runners.
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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