1-chlorosilatrane 与 MeCN 的 3:1 溶剂的 X 射线结构研究

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Mendeleev Communications Pub Date : 2024-09-01 DOI:10.1016/j.mencom.2024.09.039

Boris A. Gostevsky, Alexander V. Vashchenko, Nataliya F. Lazareva

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引用次数: 0

摘要

ClSi(OCH2CH2)3N 的单晶 X 射线研究表明，由三个硅烷分子与一个乙腈分子组成的硅烷簇具有超配位硅原子，处于三叉双锥配位环境中，O 原子位于赤道面上。因此，1-氯硅烷的一些固相结构参数和五元环的构象得到了澄清。

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X-ray structural study of 3:1 solvate of 1-chlorosilatrane with MeCN

The single-crystal X-ray study of ClSi(OCH₂CH₂)₃N showed the formation of a cluster of three silatrane molecules with one acetonitrile molecule featuring hypercoordinated Si atoms in a trigonal-bipyramidal coordination environment with O atom in the equatorial plane. A number of solid-phase structural parameters and the conformation of the fivemembered rings of 1-chlorosilatrane were thus clarified.

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.